Lecture 1 Flashcards
Aldose
Ch3-R-H
Ketose
3HC-R-CH3
Isomer
They all have the same chemical formula
Epimer
Same chemical formula but differ around 1 chiral carbon
Enantiomers
Mirror images
Pyranose
a 6 carbon cyclic sugar yields to alpha and beta
Furanose
5 carbon cyclic ring
Anomer
refer to alpha and beta formations
Alpha - Down
Beta - Up
anomeric carbon
Carbon when cyclization occurred
non reducing end
Side of the ring where it is unable to be reduced further because a reduction already occurred.
Carbonyl
R- C=O-R
Carboxylic Acid
R-C=O-OH
Hydroxyl
R-OH
Monosaccharides are classified by
number of carbons, Aldose/Ketose and Sterochem
D and L configuration
Why does cyclization run produce two anomers
The B is less sterically hindered