lattice energy Flashcards
what is first electron affinity
energy change to add 1 electron to each of 1 mole of gaseous atoms of an element
what is enthalpy change of atomisation
enthalpy change to form 1 mole of gaseous single atoms of an element from its standard state
what is enthalpy change of solution
enthalpy change to dissolve 1 mole of an ionic solid in water (to form an infinitely dilute solution)
what is enthalpy change of hydration
enthalpy change to completely hydrate 1 mole of gaseous ions (to form 1 mole of aqueous ions)
what is lattice energy
energy change when 1 mole of ionic solid is formed from its gaseous ions
how to increase polarising power of a cation
decrease radius, increase charge
how to increase polarisability of an anion
increase radius, increase charge
how to increase an ionic solid’s lattice energy
decrease ionic radii, increase ionic charges; for stronger ionic bonding
how to increase an ion’s enthalpy change of hydration
decrease radius, increase charge; for stronger attraction to water