L3 introduction to minerals Flashcards

1
Q

What is a mineral?

A

A naturally occurring inorganic solid;
with an ordered internal structure;
made up of a regular and repeating arrangement of atoms;
and a definite (but not fixed) chemical composition

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2
Q

Can gemstones be produced by industrial processes?

A

yes as there are synthetic gemstones

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3
Q

What synthetic gemstones be used for?

A

Jewellery
Communications
Laser tech
Micro-electronics
Abrasives

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4
Q

How do industrial processes mimic natural processes to produce gemstones artificially?

A

crystal growth under high temp
(high pressure- synthetic diamonds)

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5
Q

What states are almost all minerals in?

A

solid (rare exception liquid mercury)

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6
Q

What will the solid structure of minerals look like generally?

A

regular repeating three-dimensional patterns of atoms, ions or ionic groups

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7
Q

What is the chemical compositions of minerals like?

A

definite but not fixed

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8
Q

Is the ratio of cations (+) to anions (-) fixed or variable?

A

fixed

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9
Q

What can make the ratio of cations to anions in minerals more complex?

A

where different metal cations can substitute into the same structure

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10
Q

Where does crystallisation of minerals occur from?

A

Magma

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11
Q

What is magma? (not definition but what actually is it as a liquid)

A

high temperature liquid (high kinetic energy no solid stable)

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12
Q

What happens when magma cools and kinetic energy decreases? (crystallisation from magma)

A

atoms slow down enough for bonds to persist
Allows nucleation of crystals from melt

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13
Q

What can lead to larger more well formed crystals from magma?

A

if high temperatures remain, magma
partially molten, atoms still quite
mobile and move toward the surfaces of growing crystals

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14
Q

What happens if there is rapid cooling of magma? (crystal formation)

A

smaller less well formed crystals

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15
Q

What are pegmatite veins?

A

found around granites with exotic
minerals hosting rarer elements that don’t fit in “normal” silicate minerals

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16
Q

What are pegmatite veins often targeted for?

A

mineral exploitation

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17
Q

How can very water rich melts and magma bodies at late stage cooling create large crystals?

A

low viscosity
leading to very rapid crystal growth rate

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18
Q

What processes are the cause of crystal formation in solid state?

A

metamorphic

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19
Q

How can minerals form from metamorphic processes?

A

chemical reactions replacement of of current minerals with new ones

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20
Q

How are atoms transported to sites of new mineral creation? (metamorphic crystal formation)

A

bonds broken and atoms migrate by solid state diffusion or transported short distances by intergranular fluids

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21
Q

How is the mineralogy of metamorphic rocks more diverse?

A

includes minerals found in both other rock types plus high pressure / high temperature equivalents

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22
Q

How can minerals form from precipitate?

A

Precipitation from aqueous solutions containing ions of different sorts

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23
Q

What is solubility?

A

how much solid material dissolves per unit of solute

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24
Q

What physical conditions can change solubility?

A

most substances are more soluble in water at higher temperatures and higher pressures

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25
What might a decrease in temp do to solubility?
decrease in temperature (or pressure) may lead to over saturation, nucleation, and precipitation of solid (mineral) phase
26
What might loss of solute do to solubility?
may increase concentration of ions until nucleation and precipitation starts (evaporite minerals)
27
How are minerals grouped?
basis of chemical composition based on the dominant anion or anion complex
28
How many recognised minerals are there?
4150
29
how many common rock forming minerals are there?
90
30
What are native elements?
composed of a single element
31
What does it mean to metals weather?
react with oxygen and form their oxide
32
What metals are usually found in native form?
Generally only less reactive metals, such as gold, silver, copper, platinum
33
What does polymorphism mean?
same chemistry but different structure
34
What is the structure of graphite like?
carbon atoms in sheets; weak bonding -> soft
35
How is diamond formed?
formed at very high pressures
36
What is the structure of diamonds like?
carbon atoms densely packed into tetrahedral framework -> hard and strong
37
What are oxides?
Metal cations ionically bonded to oxide anions
38
What are the oxide groups?
Simple oxides Hematite group Rutile group Spinel group
39
What will simple oxides formulae look like? (X= cation)
X2O XO
40
What do hematite group oxides formulae look like?
X2O3
41
What do Rutile group oxides formulae look like?
XO2
42
What do spinel group oxides formulae look like?
XY2O4
43
What is the composition of hydroxides?
Metal cations combined with hydroxide (OH-) anions
44
How do hydroxides usually form?
at lower temperatures & are softer than oxides
45
What are hydroxides usually the product of?
Weathering or degradation
46
Where does limonite form?
fresh waters bogs
47
What is gibbsite an important component of?
aluminium bauxite ore
48
What are sulphides?
metal cations ionically bonded to sulfur anions
49
What type of condition's are sulphides indicative of?
reducing
50
What is pyrite?
fools gold
51
What conditions does pyrite form in?
sedimentary conditions under reducing / low oxygen environment
52
What is the composition of sulphates?
Metal cations ionically bonded to sulphate anions
53
What is the most important and common sulphate?
gypsum
54
What is gypsum economically important for?
component of plaster
55
Where does gypsum form?
primary evaporite minerals, formed in tropical restricted marine environments
56
What are the 3 forms of gypsum?
satin spar (fibrous), selenite (transparent), alabaster (fine-grained, massive form)
57
What is the composition of halides?
Metal cations and halogen anions
58
What 2 types of halides are common in sedimentary rock?
halite sylvite
59
How is halite typically found?
rock salt (evaporite from salt lake)
60
What is fluorite?
A halide associated with metal ores (zinc)
61
What is the composition of carbonates ?
Metal cations ionically bonded to carbonate anions
62
What is the formula for oxide anions?
O2-
63
How does alteration of minerals occur?
through oxidation and reaction with hydrous fluids or Hydrothermal fluids
64
What is formed through mineral alteration?
forms secondary minerals that reflect original mineral and alteration process
65
What is the formula for hydroxides anions?
OH-
66
What is the formula for sulphide anions?
S2-
67
What is the formula for sulphate anions?
SO42-
68
What are some examples of halogen anions?
Cl- F- Br- I-
69
What are the 3 most important and common forms of carbonates?
Calcite Aragonite Dolomite
70
What is the formula for for carbonate anions?
CO32-
71
What is the formula for metal cations involved in carbonate formation?
Ca2+
72
What is calcite?
CaCO3 dominant form of calcium carbonate
73
What is aragonite?
CaCO3 polymorph of calcite
74
What is aragonite like compared to calcite?
low temperature and metastable Often biogenic
75
What is dolomite?
(CaMg(CO3)2) associated with digenesis in reducing conditions
76
What determines the minerals that make up the rocks in the mantle and crust?
the elements that dominate the mantle and crust
77
What are silicates composed of?
Si O
78
What are some examples of silicates?
Feldspar Mica Olivine Quartz Pyroxene
79
Which mineral group is the most abundant in earths surface?
Silicates
80
What will happen if the abundance of minerals isnt enough to form a specific rock/crystal?
another will be formed which matches the conditions and abundance
81
What are igneous rocks made up of?
an assemblage of minerals that reflect the chemistry of the magma(s) that formed them, and with crystal sizes that reflect their cooling history
82
How are metamorphic rocks formed?
through mineral growth via atomic reorganisation in the solid state
83
How are sedimentary rocks formed?
from individual mineral grains, produced by weathering and erosion of other rocks, or from biomineralized materials; and/or from direct mineral precipitation
84
What is an example of the fixed cation to anion ratio?
NaCl 1:1
85
What is an example of a more complex ratio of cation to anion?
Olivine- as different metallic cations can fit into structure (Mg, Fe) can be either Fe or Mg rich
86
What will tend to alter the texture of metamorphic rocks?
stress field local conditions
87
What are some examples of liquids reaching the solubility limit?
hydrothermal settling evaporite salt stalactites and stalagmites fluorite
88
What minerals dominate earths crust?
Silicon (27%) Oxygen (47%)
89
What is the problem with having a limited number of minerals available?
it limits the ability to produce vast amounts of different rocks
90
How can gold be found in its native form?
nuggets veins
91
How can silver and copper be found in their native form?
dendritic coatings
92
Why cant all cations fit into the gaps in minerals like olivine?
They might be too big or not have the correct charge to create a stable energy balance
93
What are the silicate group of minerals built around?
silicate tetrahedral (1 silicon 4 oxygen ionically bonded)
94
What do silicate tetrahedra combine to create?
a silicate framework (different combinations create different structures)
95
What is the tetrahedra combination of olivine like?
isolated silicate tetrahedra
96
What needs to be the case for silicate tetrahedra to be electrostatically neutral?
4- charge must be balanced by positive cations between tetrahedra
97
What can the cation anion structure of olivine be like?
fixed ratio but there can be 2 cations to one anion (Mg or Fe)
98
What is the simplest form of a solid solution?
when atoms of 2 different elements can substitute for each other within a mineral structure
99
What must the atoms for a solid solution be like comparatively?
similar ionic radii same electrostatic charge
100
What does having solid solution give olivine?
variable composition restricted and defined by the nature of the holes in the structure
101
What can happen when oxygens from different tetrahedra bond? (silicate tetrahedra)
they can form chains
102
What is an example of a single chain silicate tetrahedra?
pyroxene
103
What is an example of a double chain silicate tetrahedra?
amphibole
104
What is an example of a sheet formation of silicate tetrahedra?
Mica (
105