Kinetics Flashcards

1
Q

factors that influence reaction rate

A
  1. concentration
  2. physical state
  3. temperature
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

reaction rate:

concentration (2)

A
  • molecules must collide to react

- Increase # molecules, increase # of collisions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

reaction rate:

physical State

A
  • molecules must mix to collide

- increased Surface Area, faster reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

reaction rate:

temperature

A
  • molecules must collide with enough energy to react

- Increase temp, increase reaction rate due to ^ in energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

___ [reactants], [products] ____

A

decrease, increase

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Rate equation

A

rate = k x [A]m x [B]n

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

m=1

A

if the rate doubles when [A] doubles

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

m=2

A

if the rate quadruples when [A] doubles

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

m=0

A

if the [A] doubles but no change in the rate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

1st order rate =?

A

k[A]

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

2nd order rate=?

A

k[A]2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

zero order rate=?

A

k

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

1st order rxn? (2)

A

ln[A]f-ln[A]i=-kt

ln[A]f=-kt+ln[A]i

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

2nd order rxn?

A

1/[A]f=kt+1/[A]i

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

zero order rxn?

A

[A]f=-kt+[A]i

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

half life 1st order

A

t1/2=ln x 2/k

17
Q

half life 2nd order

A

t1/2=1/k[A]i

18
Q

half life zero order

A

t1/2=[A]i/2k

19
Q

arrhenius equation

A

k=Ae^-EA/RT

20
Q

as temp ___, # of molecules with a high EA ___

A

increase, increase

21
Q

___ EA, ___ product formation

A

increase, decrease

22
Q

molecularity

A

each steps # of reactants

23
Q

uni-molecular

A

1 reactant

24
Q

bimolecular

A

2 reactants

25
Q

termolecular

A

3 reactants

26
Q

catalyst

A

a substance that increases rate but is not consumed, they lower activation energy of the reaction

27
Q

homogeneous catalyst

A

existing in same solution mixture

28
Q

heterogeneous catalyst

A

speed up rxn but in different phases