Chapter 11 Flashcards

1
Q

C and H together are always what IMF?

A

London

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2
Q

Heating Curve for water:

Q1=

A

q1 = m x Csice x Delta t

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3
Q

Heating Curve for water:

Q2=

A

q2 = m x delta Hfus

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4
Q

Heating Curve for water:

Q3=

A

q3 = m x Csliquid x Delta t

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5
Q

Heating Curve for water:

Q4=

A

q4 = m x Delta Hvap

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6
Q

Heating Curve for water:

Q5=

A

q5 = m x Csgas x Delta t

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7
Q

Cs is

A

Specific heat in J/(g)(c)

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8
Q

m for heating curve is

A

mass in grams

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9
Q

relationship between IMF and Temp…

A
  1. As temp DECREASES, imf INCREASES

2. As temo INCREASES, imf DECREASES

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10
Q

All molecules have this IMF

A

London forces

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11
Q

An instantaneous dipole or temporary dipole is created is called

A

London Force

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12
Q

___ electron cloud, ____ Zeffect, ____IMF

A

increases, decreases, increases

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13
Q

Relationship between molar mass and boiling point…

A

^ Molar Mass, ^ Boiling Point

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14
Q

Relationship between Surface Area and Energy needed to get into vapor phase

A

^ Surface Area, ^ amount of energy needed to get into vapor phase

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15
Q

This IMF exists in all polar molecules

A

Dipole-Dipole

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16
Q

The relationship between molar mass and boiling point is only true for which IMF

A

London Forces

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17
Q

Typical Energy Range for Dipole-Dipole

A

5-25 kj/mol

18
Q

Typical Energy range for London forces

A

0.05-40kj/mol

19
Q

Hydrogen bonds directly to which small electronegitive atoms?

A

F, O, N

H(FON)

20
Q

Typical Energy range for hydrogen forces

A

10-40jk/mol

21
Q

IMF that forms from a ionic and polar compound

A

Ion-Diople

22
Q

typical energy range for Ion-Dipole forces

A

40-600kj/mol

23
Q

Surface tension is…

A

the resistance of liquid to spread out

24
Q

Relationship between surface area and IMF

A
  1. as surface tension v , IMF v

2. as surface tension ^, IMF ^

25
Q

Viscosity is…

A

measurement of a substances resistance to flow

26
Q

Relationship between Viscosity and IMF

A

viscosity ^, IMF ^

27
Q

Relationship between Viscosity and Molecular weight

A

viscosity ^ , molecular weight ^

28
Q

Relationship between Viscosity and the length of the molecule

A

viscosity ^ as the length of a molecule ^

29
Q

Capillary action is…

A

ability of liquid to flow against gravity

30
Q

Cohesive forces..

A

Attraction of molecules in the liquid

C > A

31
Q

Adhesive Forces…

A

Attraction of molecules and the surface of tube

A > C

32
Q

Relationship between vaporization rate and Temp

A

^ vaporization rate, ^ temp

33
Q

Relationship between vaporization rate and surface area

A

^ V.R, ^ S.A

34
Q

Relationship between vaporization rate and IMF

A

v V.R, ^ IMF

35
Q

Clausis-claypyron equation: 2 point

A
ln(P2/P1) = (-delta Hvap/R)(1/T2 - 1/T1)
R= gas constant = 8.314
Pvap= vapor pressure
T= Temp
36
Q

Solid to liquid

A

Fusion, Delta Hfus (+)

37
Q

liquid to solid

A

freezing, Delta Hfus (-)

38
Q

liquid to gas

A

vaporization, delta Hvap (+)

39
Q

gas to liquid

A

condensation, Delta Hvap (-)

40
Q

solid to gas

A

Sublimation, Delta Hsub (+)

41
Q

gas to solid

A

deposition, delta Hsub (-)