Kinetics Flashcards
Collision theory
For reactions to occur particles must collide
Particles must have enough energy to “overcome energy barrier” to be able to react
Minimum energy to overcome the barrier is activation energy
Increasing concentration
Increases number of reacting particles in given volume
Increases frequency of collisions
More successful collisions in a given time
Increasing pressure
More particles in a given volume Increases
More successful collisions in a given time
Increasing surface area
Increases number of reactant particles available for collision
Increases frequency of collisions
More successful collisions in a given time
Increasing temperature
Particles have more Kinetic energy
More particles have energy greater than activation energy
More successful collisions in a given time
Has the greatest effect on rate of reaction
Effect of catalyst on rate of reaction
Increases rate of reaction
Provides alternative reaction pathway with lower activation energy
Maxwell Boltzmann