Key Stuff - Module 3 + 5 Flashcards
1st ionisation energy
removal of 1 mole of electrons from 1 mol of gaseous atoms
Periodicity
Repeating trends in physical + chemical properties
Metallic bonding
Strong electrostatic attraction bt/w positive ions + delocalised electrons
Disproportionation
Oxidation + reduction of the same element
Activation Energy
Minumum energy required for a reaction to take place
Enthalpy change of formation
Formation of 1 mol of compound froms its elements
Enthalpy change of combustion
Compete combustion of 1 mol of a substance
Enthalpy change of neutralisation
Formation of 1 mol of water from neutralisation
Average bond enthalpy
Breaking of 1 mol of bonds in gaseous molecules
Homogenous catalyst
Same phase a reactants
Heterogeneous catalyst
Different phase as reactants
Bronsted-Lowry acid
Donates a proton
Bronsted-Lowry Base
Accepts a proton
What indicator should you use for strong acid + strong base reaction
Phenolphalein or methyl orange
Strong acid + weak base
Methyl orange
Weak acid + strong base
Phenolphthalein
Weak acid + weak base
pH at equivalence - depends on the relative strength of acid + base
Lattice enthalpy
Formation of 1 mol of ionic lattice from gaseous ions
Enthalpy change of solution
Dissolving of 1 mol of solute
Enthalpy change of hydration
Dissolving of 1 mol of gaseous ions in water
Entropy
Measure of dispersal of energy in a system which is greater, the more disorder a system
Standard electrode potential
Is a measure of the reducing power of any element or compound
Units for rate constant (k)
Rate graphs for 0 order reaction
Rate graphs for 1st order
Rate graphs for 2nd order
Rate determining step info
- Slowest step is rate determining step
- Species involved in this step are found in overall rate equation
Weak acids
Partially dissociate into ions in aqueous solutions
Strong acids
Completely dissociate into ions in aqueous solutions releasing H+ ions
Name 3 basic strong acids
- HCl
- HNO3
- H2SO4
Name a basic weak acids
Carboxylic acids eg ethanoic acid
Name 3 basic strong bases
- NaOH
- KOH
- Ba(OH)2
Name a weak base
Ammonia (NH3)
State the redox reaction bt/w manganate (VII) + iron (II)
Describe the method you would use to do a redox titration calculation
- Form redox equation
- FInd the moles of compound
- Use redox equation to find the moles of unknown
- Scale up if needed
What must you remember when calculating elctrode potential
Reduced electrode potential is always more positive electrode potential
Explain the process of a proton exchange fuel cell
- Hydrogen gas enters system
- Hydrogen oxidised to H+ at anode
- Electrons travel via external circuit
- H+ ions travel through electrolyte + membrane
- oxygen gas enters cell
- Oxygen is reduced at cathode
- Catalyst speeds up reaction bt/w oxygen + H+
- Water produced
Advantages of fuel cells
- Eliminate pollution caused by burning fossil fuels
- Eliminates green house gases if hydrogen used comes from electrolysis of water
- Higher efficiency than diesel or gas engines
Alkaline Fuel Cells (AFC)
- Uses alkaline electrolyte eg KOH
- Used by NASA in space shuttles
Direct Methanol Fuel Cells (DMFC)
- Uses polymer membrane as electrolyte
- Catalyst on anode draes hydrogen from liquid methanol
- Eliminates need for fuel reformer, pure methanol can be used as fuel
Rearranged Arrhenius equation for Ea
Ea = RT (lnA-lnk)
Rearranged Arrhenius equation for A
Rearranged Arrhenius equation for T
T = Ea / R (lnA-lnk)