June 2016 Paper 1 Flashcards

1
Q

This question is about electron configuration.
Give the full electron configuration of an Al atom and of a Cr3+ ion.

Al atom :

Cr3+ ion :

A

This question is about electron configuration.
Give the full electron configuration of an Al atom and of a Cr3+ ion.

Al atom : 1s2 2s2 2p6 3s2 3p1

Cr3+ ion : 1s2 2s2 2p6 3s2 3p6 3d3

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2
Q

Give the electron configurations for copper and chromium and state why these exceptions apply to only these elements

In the case of chromium by …

Cr:

In the case of copper by …

Cu:

A

The 3d sub shell is more stable when its either half full or completely full

In the case of chromium by only having one electron in the 4s sub shell, it can have a full 3d sub shell

Cr: 1s2 2s2 2p6 3s2 3p6 3d5 4s1

In the case of copper by only having one electron in the 4s sub-shell it can have a completely full 3d sub shell

Cu: 1s2 2s2 2p6 3s2 3p6 3d10 4s1

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3
Q

The trend of atomic radius?

State why

A

The trend of atomic radius?

Atomic radius increases down a group and across a period from the left to right

This is caused by the increase in the number of protons and electrons across a period. (One proton has a greater effect than one electron; thus, electrons are pulled towards the nucleus, resulting in a smaller radius. Atomic radius increases from top to bottom within a group. This is caused by electron shielding.)

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4
Q

Which of these atoms has the largest radius?

Mg

Na

Ar

Cl

A

Na

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5
Q

Which of these atoms has the smallest number of neutrons

3H

4He

5He

4Li

A

Li

7-4

=3

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6
Q

Which change requires the largest amount of energy?

He+(g) —-> He2+(g) + e-

Li(g) —-> Li+(g) + e-

Mg+(g) ——> Mg2+(g) + e-

N(g) —> N+(g) + e-

A

He+ —-> He2+(g) + e-

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7
Q

Which one of the following is a correct electron arrangement?

A Cu+ is [Ar]3d94s1

B Cu is [Ar]3d104s2

C Cu2+ is [Ar]3d84s1

D Cu+ is [Ar]3d10

A

Which one of the following is a correct electron arrangement?

D Cu+ is [Ar]3d10

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8
Q

Chlorine has two isotopes, 35Cl and 37Cl. The number of molecular ion peaks in the mass spectrum of a sampleofCl2 is

A 2

B 3

C 4

D 5

A

3

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9
Q

Use the Periodic Table to deduce the full electron configuration of calcium.

A

Use the Periodic Table to deduce the full electron configuration of calcium.

1s2 2s2 2p6 3s2 3p6 4s2

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10
Q

What products are formed in the reaction of calcium and excess water

A

Calcium hydroxide and hydrogen gas are generated when calcium reacts with water. This is a single displacement reaction.

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11
Q

Write an ionic equation, with state symbols, to show the reaction of calcium with an excess of water

State the role of water in the reaction with calcium

A

Ca(s)+ 2H O(l) Ca2+(aq) + 2OH–(aq) + H (g)

Oxidising agent

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12
Q

Write an equation to show the process that occurs when the first ionisation energy of calcium is measured.

A

Write an equation to show the process that occurs when the first ionisation energy of calcium is measured.

Ca(g) —-> Ca+(g) + e-

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13
Q

State and explain the trend in the first ionisation energies of the elements in Group 2 from magnesium to barium

Trend:

Explanation …

A

State and explain the trend in the first ionisation energies of the elements in Group 2 from magnesium to barium

Trend: decrease

Explanation: Ions get bigger so
Weaker attraction of ion to lost electron

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14
Q

This question is about the elements in Period 3 of the Periodic Table.

State the element in Period 3 that has the highest melting point. Explain your answer

A

Sillicon

Has many covalent bonds that require a lot of energy to break

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15
Q

State the element in Period 3 that has the highest first ionisation energy. Explain your answer.

Element

Explanation

A

State the element in Period 3 that has the highest first ionisation energy. Explain your answer.

Element
Argon

Explanation
Large(st) number of protons
Same amount of shielding

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16
Q

Suggest the element in Period 3 that has the highest electronegativity value.

A

Suggest the element in Period 3 that has the highest electronegativity value.

Chlorine