Isomers Flashcards
Isomerism
Isomerism is when molecules have the same molecular formula but a different arrangement of atoms within their space.
Structural isomerism
When molecules have the same molecular formula but a different structural formula.
What are the three types of structural isomerism?
Positional
Functional Group
Chain
Positional isomerism
Same molecular formula, functional group is attached to the main chain at different points.
Functional Group isomerism
Same molecular formula, different functional groups.
Chain isomerism
Same molecular formula, hydrocarbon chains arranged differently.
Stereoisomerism
Have the same molecular and structural formula, but the arrangement of atoms and bonds in their space differs.
What are the two types of stereoisomerism?
E-Z isomerism
Optical isomerism
E-Z isomerism
Same molecular and structural formula, but the arrangement of the substituents on either side of the carbon-carbon double bond differ.
Optical isomerism
Same molecular and structural formula, but the four different substituents attached to one carbon atom (a chiral carbon) are arranged different within the space and are non-superimposable mirror images of one another.