Ionic, covalent (and metalic) bonding Flashcards
Ions
Ions are formed by the loss (form positive ions) or gain (form negative ions) of electrons by atoms.
Ionic bonding occurs between a metal wanting to lose electron(s) and a nonmetal wanting to gain
electron(s).
What are the charges of all the Groups?
G1 = +1
G2 = +2
G3 = +3
G5= -3
G6 = -2
G7 = -1
Bonding
Electrostatic forces of attraction between oppositely charged ions
Ionic bonding
METAL and NON-METAL
- Occurs between a metal wanting to lose electron(s) and a non-metal wanting to gain electron(s)
- Electrons are transferred from the metal to the non-metal and how many each atom gains or loses
Physical properties of ionic bonding
- High melting points – oppositely charged ions strongly attract and it takes a lot of energy to break this attraction
- Conduct when molten or aqueous – ions free to move and carry the charge. When solid the ions are not free to move and so cannot conduct
Covalent bonding
NON-METALS
- Formed between atoms by the sharing of a pair of electrons
- Strong electrostatic forces of attraction between bonding/shared pair of electrons and both nuclei of the two atoms.
- Generally do not conduct electricity as do not possess delocalised electrons which are free to move.
Simple molecular covalent
- Gases of liquids, or solids with low melting and boiling points
- As they have low boiling points they have weak intermolecular forces of attraction which require very little
heat energy to break. - Their melting and boiling points increase with increasing relative molecular mass as they contain more electrons and therefore have stronger intermolecular forces which require more energy to break
- They do not conduct electricity as they possess no delocalised electrons to carry
the charge and have no overall electric charge.
Graphite (covalent structure)
- Each carbon atom is bonded to three others. It, therefore, has one free delocalised electron for every carbon atom. These delocalised electrons can move through the structure and conduct electricity.
- It has a high melting point as it is a giant covalent structure with very strong bonds.
- It possesses weak intermolecular forces of attraction between the hexagonal layers which mean they can slide over each other and be used as a lubricant.
Diamond (covalent structure)
- Giant covalent structure/lattice with each carbon atom strongly bonded to four other carbon atoms. As it possesses strong covalent bonds throughout its structure it has a high melting point as it takes a lot of heat energy to break them
- It is used as a cutting material on drills
- Each carbon atom is bonded to four others so no free delocalised electrons and therefore does not conduct electricity like graphite