investment materials Flashcards
how many type of gypsum bonded investment are there and what are each used for
type1: for inlays and crowns, casting shrinkage manily comprensated by thermal expansion
type 2 for inlay and crown, casting shrinkage mainly compensated by hygroscopic expansion
type3 for construction of partial dentures w gold alloy
what is gypsum bonded investment use for
alloys that melt <1300deg
what is added to protect molten metalfrom SO2 that is realeased during decomposition of investment greater than 700deg
oxalatae decomposes during heating to form CO2 in the mould
what is the composition of gypsum bonded investment
1.a-hemihydrate of gypsum
dental stone used bc stronger than plaster
serves as binder to hold other constituents, provides rigidity
- silica
provides refractory(high temp strength during heating), regulates thermal expansion, types of silica commonly used are quartz cristobalite - reducing agents like carbon and powdered copper
provide reducing atmosphere in mould when alloy is used - modifying agent like boric acid and nacl
prevent shrinkage of gypsum when heated over 300deg, regulates setting expansion and time - colouring agent
what is the temp from a-quartz to b-quartz
575 degree
what is the temp from a-cirstobalite to B-cristobalite
200-270deg
does setting expansion increase with silica?
yes, silica interfere with intermeshing and interlocking of crystals as they form
what is the theory of hygroscopic expansion
immersion water replaces water of hydration, prevent confinement of growing crystals by surface tension of excess water
diluent effect of silica particles lead to expansion greater than gypsum alone
what is the max expansion permitted by hygroscopic expansion, and how do you achieve that of gypsum bonded invetsment
max expansion is 2.2%, set it under water
how does silica present affect thermal expansion of gypsum bonded investment
more silica more thermal expansion. Cristobalite expand to a greater extent than quartz
what are some factors affecting thermal expansion of gypsum bonded investment
- water powder ratio, increase ratio, decrease thermal expansion
- add chemical modifiers like chlorides of Na/K/Li, eliminates contractionf of gypsum when <700deg, increase thermal expansion without excessive silica
how does thermal shrinkage of gypsum bonded investment occur
when investment cool fro 700deg, B invert to a- form, contraction until less than original dimension
what are some factors influencing strength of gypsum bonded investment
- type of gypsum binder: dental stone>dental plaster
- water powder ratio, increase ratio decrease strength
- chemical modifiers: allow more gypsum binder to be used can increase strength
what are phosphate bonded investment used for
for alloys that melt >1300degree
what does mixing phosphate bonded powder in special liquid do
decreases thermal expansion, increases strength. Can expand hygroscopically