Introduction to organic chemistry Flashcards

1
Q

What does the general formula show?

A

It is a formula that describes any member of a family of compounds

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2
Q

What is the Empirical formula?

A

The simplest ratio of atoms of each element in a compound

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3
Q

What does the Molecular formula show?

A

The actual number of atoms of each element in a molecule

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4
Q

What does the Structural formula show?

A

This formula shows the atoms carbon by carbon with the attached hydrogens and functional groups and how they are arranged

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5
Q

What does the Skeletal formula show?

A

This formula shows the bonds of carbon skeleton only with any functional groups attached

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6
Q

What does the Displayed formula show?

A

This formula shows how all the atoms are arranged and all the bonds between them

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7
Q

What is a homologous series?

A

A homologous series is a family of compounds with the same general formula and functional group.

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8
Q

What is a functional group?

A

A reactive part of the molecule that is responsible for most of the chemical properties

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9
Q

How does each successive member of a homologous series differ from the other?

A

They differ by a CH(2) group

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10
Q

What is the suffix for alkanes?

A

-ane

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11
Q

What is the prefix for branched alkanes?

A

alkyl-

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12
Q

What is the suffix for alkenes?

A

-ene

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13
Q

What are the prefixes for halogenalkanes?

A

fluoro-
chloro-
bromo-
iodo-

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14
Q

What is the suffix for alcohols?

A

-ol

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15
Q

What is the suffix for aldehydes?

A

-al

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16
Q

What is the suffix for ketones?

A

-one

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17
Q

What is the suffix for carboxylic acids?

A

-oic acid

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18
Q

What is the prefix and suffix for esters?

A

alkyl-

-oate

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19
Q

What is the suffix for amines?

A

-amine

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20
Q

What is the suffix for amides?

A

-amide

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21
Q

What is the suffix for acyl chlorides?

A

-oyl chloride

22
Q

What is the prefix and suffix for cycloalkanes?

A

cyclo-

-ane

23
Q

What is the prefix for arenes?

24
Q

What are lone pairs?

A

Electrons not involved in a bond

25
What are hydrocarbons
A compound containing only hydrogen and carbon
26
What is the definition of saturated?
A comppound containing single carbon to carbon bonds
27
What is the definition of unsaturated?
Acompoud containing a double carbon to carbon bond
28
What is an alkyl?
An alkyl is made when a hydrogen is removed from an alkane. They are often attached to organic molecules
29
What is structural isomerism?
Molecules with the same molecular formula but different structures
30
What are the three type of structural isomerism?
Chain Functional Positional
31
What are chain isomers?
Structural isomers that differ by having a different carbon chain
32
What are functional isomers?
Structural isomer that differ by having a different functional group
33
What are positional isomers?
Structural isomers that differ by having the functional goup in a different position
34
What is the priority from highest to lowest when it comes to naming organic compounds?
``` Carboxylic acid ester acyl chloride nitrile aldehyde ketone alcohol amine alkene halogenalkane ```
35
What are stereoisomers?
Molecules with the same molecular and structural formulae but different spatial arrangement of atoms
36
What are the two different types of stereoisomers?
Geometric | Optical
37
What are geometric isomers?
Molecules which have a different arrangement of group around the C=C Also known as E-Z stereisomers
38
What are optical isomers?
Molecules which are non-superimposable mirror images
39
When does geometric isomerism occur?
Restricted around the C=C bond | There are different groups/atoms attached at both ends of the C=C bond
40
What are the prefixes for the number of carbons from 1 to 10
``` 1- meth 2- eth 3- prop 4- but 5- pent 6- hex 7- hept 8- oct 9- non 10- dec ```
41
What are the rules for naming straight chain alkanes?
-Count the carbons in the main chain -Use the correct prefix for the number of carbons Add the suffix for alkanes at the end
42
What are the rules for naming branched alkanes?
Name the main carbon chain Add the name for the side chain Number where the chain is added to the main chain so that it is the lowest it can be When there are two or more side chains, list them alphabetically use the prefixes di-, tri-, tetra etc, if necessary
43
What are the rules for naming alkenes?
Find the longest carbon chain that contains the double chain Name the alkene(-ene suffix) Number the carbons so that the C=C bond has the lowest number State the number before the -ene with a hyphen(eg. hex-1-ene
44
What are the rules for naming haloalkanes?
Name the haloalkane by naming the alkane and then the halogen Use numbers to show where the halogen is Make sure the number is as low as possible Remember to list the groups alphabetically Use di-, tri- etc if appropriate
45
What are the different type of haloalkanes?
Primary Secondary Tertiary
46
What is primary haloalkane?
A carbon joined to halogen is only attached to one other alkyl group
47
What is secondary haloalkane?
A carbon joined to halogen is only attached to two other alkyl group
48
What is tertiary haloalkane?
A carbon joined to halogen is only attached to three other alkyl group
49
What is a Z-isomer?
A z-isomer has the same groups either above or below the C=C bond
50
What is an E-isomer?
An e-isomer has 2 of the same group positioned across the C=C bond
51
What is the IUPAC system?
It is the agreed international language of chemistry. | It means that scientific ideas can be shared effectively by scientists across the globe which avoids confusion