Group 2 Flashcards

1
Q

What do all group 2 elements in common?

A

They have 2 electrons in their outer shell

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2
Q

What happens when group 2 elements react?

A

They lose 2 electrons and form 2+ ions

M(g) –> M(g)2+ + 2e-

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3
Q

What is the trend for the atomic radius down the group?

A

The atomic radius increases down the group

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4
Q

Why does the atomic radius increase?

A

There are extra electron shells as you go down the group

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5
Q

What is the trend for the first ionisation energy down the group?

A

The first ionisation energy decreases down the group

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6
Q

What factors cause the first ionisation energy to decrease?

A
  • Each element down group 2 has an extra electron shell compared to the one above
  • The inner shells shield the outer electrons from the attraction of the nucleus
  • The outer electrons are further away from the nucleus which reduces the force of attraction
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7
Q

What is the trend in the reactivity down the group?

A

The reactivity increases down the group

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8
Q

Why does the reactivity increase down the group?

A

When the elements react, they lose electrons.

The easier it is to lose electrons, the more reactive the element

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9
Q

In group 2, when is it easier to lose electrons?

A

First and second ionisation energies

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10
Q

What is the general trend for melting points down the group?

A

The melting points generally decrease down the group

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11
Q

What type of structure does group 2 element have?

A

They have a giant metallic structure with positive ions surrounded by delocalised electrons from the outer electron shells

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12
Q

Why do the melting points decrease down the group?

A

The larger the ionic radius, the further away the delocalised electrons are from the nucleus and the lower the force of attraction.
Therefore, less energy is needed

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13
Q

Why is there a large drop in the melting point between beryllium and magnesium?

A

The metallic structure changes

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14
Q

What other name is given to group 2?

A

Alkaline Earth metals

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15
Q

Why is group 2 called alkaline earth metals?

A

Their oxides and hydroxides are alkaline

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16
Q

Which hydroxides are sparingly soluble?

A

Mg(OH)2

Ca(OH)2

17
Q

Why are Mg(OH)2 and Ca(OH)2 sparingly soluble?

A

Their reactions with water are reversible

This means that the reactions are not complete

18
Q

Why are Sr(OH)2 and Ba(OH)2 soluble in water?

A

These metals are more reactive than Ca and Mg

Their reactions are not reversible as they react fully

19
Q

What can be observed as the metals react with water?

A

Down the group

  • more vigorous fizzing
  • faster dissolving
  • the solution heats up
  • less precipitation
20
Q

What happens when magnesium reacts with steam?

A

Magnesium oxide and hydrogen are produced

Mg(s) + H20(g) → MgO(s) + H2(g)

21
Q

What is the trend in the solubility of the hydroxides of group 2 elements, Mg-Ba?

A

The solubility increases down the group

22
Q

What is the trend in the solubility of the sulfates of group 2 elements, Mg-Ba?

A

The solubility decreases down the group

23
Q

Which sulfate is insoluble?

A

BaSO4

24
Q

How is Mg(OH)2 used in medicine?

A

It is a weak alkali and used in the acid neutralisation in the stomach(indigestion)

25
Q

How is BaSO4 used in medicine?

A

Barium meals

It is opaque and used for live x-rays to diagnose problems in the digestive system

26
Q

How is Ca(OH)2 used in agriculture?

A

It is used in the neutralisation of the acidic soil

27
Q

What is the ionic equation for the neutralisation in both cases of Ca(OH)2 and Mg(OH)2?

A

H+(aq) + OH-(aq) → H2O(l)

28
Q

What is magnesium used to extract?

A

Titanium

29
Q

What is the process for the extraction of titanium?

A

The titanium ore is converted to titanium chloride by heating it with carbon is a stream of chlorine gas
Titanium chloride is then purified by fractional distillation before being reduced by magnesium in a furnace

30
Q

What is the equation for the extraction of titanium?

A

TiCl4(g) + 2Mg(l) → Ti(s) + 2MgCl2(l)

31
Q

Why is titanium desired?

A

It is a very strong metal

E.g. it is used in the bodies of modern planes

32
Q

How are calcium oxide and calcium carbonate used?

A

They are used to remove sulphur dioxide

33
Q

What is wet scrubbing?

A

The process of removing acidic sulphur dioxide from flue gases by reacting with an alkali

34
Q

What are the equations for the reaction of sulphur dioxide with calcium oxide or calcium carbonate?

A

CaO(s) + SO2(g) → CaSO3(s)

CaCO3(s) + SO2(g) → CaSO3(s) + CO2(g)

35
Q

How would you test for sulphate ions?

A

Adding acidified barium chloride to a solution containing sulfate ions which would form a white precipitate of barium sulfate

36
Q

Why does the barium chloride need to be acidified before added to the solution?

A

Acidifying the barium chloride means that any carbonates can be removed as carbonates produce white precipitates too
This would produce a false positive result

37
Q

What is the ionic equation for the reaction of acidified barium chloride with the sulfate solution?

A

Ba(2+)(aq) + SO4(2-)(aq) → BaSO4(s)