Introduction to Metabolism Flashcards
Metabolism
a sum of all chemical reactions in a cell or organism
Metabolic pathway
a sequence of chemical reactions undergone by a compound in a living organism
Catabolism
complex molecules are broken down into simple molecules
Anabolism
build complex molecules from simple sugars
oxidation
a reaction in which a molecule loses electrons
reduction
a reaction in which a molecule gains electrons
Kinetic energy
energy in motion
ex. water spilling over a damn can be harnessed to do eo work since its in motion. Heat and light, heart muscles contraction.
Potential energy
stored energy by virtue of an objects position within an attractive or repulsive force field
ex. water backed up behind a dam is not doing any work, but could do work if released.
Work
is the transfer of energy from one body to another
ex, apple falling, potential energy is converted into kinetic energy when the apple falls. As the speed increases, the apple looses potential energy and gains kinetic energy.
thermodynamics
branch of science dealing with the laws and theories related to energy in the universe. Theres 2 laws.
first law of thermodynamics
states that the total amount of energy in the universe is constant. Energy cannot be created nor destroyed but only converted from one form to another.
Bond energy
the measure of stability of a covalent bond. different molecules have different stabilities.
Potential Energy diagrams
shows the changes in potential energy that takes place during chemical reaction
Activation energy
the difference between the potential energy level and the transition state and the potential energy of reacting molecules.
Transition state
in a chemical reaction a temporary condition in which the bonds within the reactants are breaking and the bonds between products are forming.
enthalpy
over all change in energy that takes place in a reaction
endothermic reaction
delta H is positive
exothermic reaction
delta H is negative
Entropy
a physical property and it is a measure of disorder or uncertainty about a system
Entropy increases when disorder increases
ex. solid reactants become liquid or gaseous products
- liquid reactants become gaseous products
Gibbs free energy
energy that can do useful work, also called Gibbs free energy
delta G neg. is spontaneous, pos. is not spontaneous
Second Law of thermodynamics
any time you do work, including any time you make energy transformation, some of the starting energy is going to be lost as heat
Major complications:
- no process is 100% efficient
Coupling free energy - yielding
which is (exergonic) catabolic process with energy-requiring (endergonic) anabolic process, living things build up their bodies around them.
Exergonic reactions
chemical reaction in which the energy of the products is less then the energy of reactants
ex. cellular respiration
Endergonic reactions
chemical reaction which the energy of the products is more than the energy of reactants
ex. Photosynthesis
Why Metabolic pathways are reversible?
Metabolic reactions are enzymes catalyzed and are reversible, when a reversible reaction reaches an equilibrium its delta G = zero and its free energy content is zero.
A cell whose reversible reactions reach equilibrium is a dead cell