Intermolecular Forces- Dispersion/Dipole/Hydrogen Flashcards
What are intermolecular forces?
Forces of attraction BETWEEN Molecules
Intermolecular Forces determine ___________ properties
Intermolecular Forces determine PHYSICAL properties
Intramolecular forces are __________ than Intermolecular Forces
Intramolecular forces are STRONGER than Intermolecular Forces
Dispersion Forces are the _______ of van der waals forces
Dispersion Forces are the WEAKEST of van der waals forces
The Larger the molecule the stronger the dispersion forces, Why? E.g The melting points of gases increase with their atomic mass as there are stronger dispersion forces as the molecules are larger
There is a stronger attraction as there are more protons and electrons present.
Dispersion forces are stronger in LINEAR or COMPACT molecules
LINEAR molecules have stronger dispersion forces as there is more surface interaction between molecules compared to compact shapes.
What are Dipole- Dipole forces?
Dipole-Dipole forces form due to differences in the electronegativities. These Polar Bonds result in the electrons being attracted to the nucleus of a higher electronegativity.
Dipole-Dipole Attraction is more significant for ____________ molecules.
Dipole-Dipole Attraction is more significant for SMALLER molecules.
What is Hydrogen Bonding?
An extreme form of dipole-dipole interactions, therefore a greater strength between molecules.
When does Hydrogen Bonding occur?
When Hydrogen is covalently bonded to - Nitrogen -Oxygen - Flurine on a neighbouring molecule.
Not the N, O, or F don’t have to be the centeral atom, only bonded to Hydrogen.
Boiling Point ___________ with Hydrogen bonding because_____________
Boiling Point Increases with Hydrogen bonding because the bonds are stronger between molecules
How can a substance without H Bonds have a higher melting point. E.g CCl4 has a higher melting point that CH3OH
Although Hydrogen Bonds may be present, since CCl4 is a larger molecule, it has stronger dispersion forces compared to methanol, in addition to its dipole-dipole interactions.
In which state of matter are Intermolecular forces strongest?
Solid- there is a greater attraction between particles as they are held together closely.