Intermolecular forces and colligitive properties Flashcards

1
Q

intermolecular bonds are weaker than

A

covalent

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2
Q

dipole-dipole forces

A

attractive force between 2 polar molecules

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3
Q

dipole-dipole forces increase as

A

dipole of molecules increase

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4
Q

hydrogen bonding

A

very strong dipole-dipole interaction, occurs when H is covalently bonded to a highly electronegative atom

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5
Q

hydrogen bonding occurs between H and _____

A

O, F, N

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6
Q

the more hydrogen bond donors and acceptors, ________

A

the higher the difference in properties

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7
Q

Ion-dipole forces

A

an ion interacts with a polar molecule (ex:water)

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8
Q

dispersion forces

A

caused by induced dipole when electrons from other molecules repel each other

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9
Q

what molecules posses dispersion forces

A

all of them

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10
Q

polarizability

A

ability to “move” outer electrons

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11
Q

polarizability trends

A

increases going down a group (column)

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12
Q

Van der Waals Forces

A

term for all intermollecular forces

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13
Q

rank intermollecular forces from weakest to strongest

A

dispersion, dipole-dipole, hydrogen bonding

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14
Q

strength of dispersion forces is related to

A

molecular weight (low = less)

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15
Q

solutions

A

homogeneous mixtures of 2 or more substances

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16
Q

in a solution, the ____ is dispersed evenly throughout the ____

A

solute, solvent

17
Q

charge of ΔH for separation of solute particles

A

+ (endothermic)

18
Q

charge of ΔH for the separation of solvent particles

A

+ (endothermic)

19
Q

charge of ΔH for the new interactions between solvent and solute

A
  • (exothermic)
20
Q

charge of ΔS for formation of solution

21
Q

saturated solution

A

the solvent holds as much solute as possible at that temp

22
Q

unsaturated solution

A

less solute than can dissolve in the solvent at that temp

23
Q

supersaturated solution

A

the solvent holds more solute than is normally possible at that temp

24
Q

polar substances tend to dissolve in

A

polar substances

25
adding nonpolar chains (CH groups) increases _____
solubility in nonpolar solvent
26
if a molecule has an OH it is ____
polar
27
colligative properties depend on
only the number of solute particles
28
solutions of electrolytes should show ______ changes than those of nonelectrolytes
greater
29
how is vapor pressure effected by adding solute
higher concentrations of nonvolatile solutes make it harder to escape to the vapor phase, lowering vapor pressure
30
how is boiling point effected by adding solute
increase boiling point
31
how is freezing point affected by adding solute
lowers freezing point
32
ΔT is ____ to find new boiling point and ____ to find new freezing point
added, subtracted
33
nonelectrolytes
organic molecules
34
osmosis
a net movement of solvent from a high area of high solvent concentration (low solute) to low solvent concentration (high solute)
35
osmotic pressure
pressure required to stop osmosis
36
colloids
suspensions of particles larger than individual ions, but too small to be settled out by gravity