Intermolecular forces and colligitive properties Flashcards

1
Q

intermolecular bonds are weaker than

A

covalent

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2
Q

dipole-dipole forces

A

attractive force between 2 polar molecules

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3
Q

dipole-dipole forces increase as

A

dipole of molecules increase

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4
Q

hydrogen bonding

A

very strong dipole-dipole interaction, occurs when H is covalently bonded to a highly electronegative atom

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5
Q

hydrogen bonding occurs between H and _____

A

O, F, N

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6
Q

the more hydrogen bond donors and acceptors, ________

A

the higher the difference in properties

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7
Q

Ion-dipole forces

A

an ion interacts with a polar molecule (ex:water)

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8
Q

dispersion forces

A

caused by induced dipole when electrons from other molecules repel each other

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9
Q

what molecules posses dispersion forces

A

all of them

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10
Q

polarizability

A

ability to “move” outer electrons

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11
Q

polarizability trends

A

increases going down a group (column)

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12
Q

Van der Waals Forces

A

term for all intermollecular forces

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13
Q

rank intermollecular forces from weakest to strongest

A

dispersion, dipole-dipole, hydrogen bonding

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14
Q

strength of dispersion forces is related to

A

molecular weight (low = less)

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15
Q

solutions

A

homogeneous mixtures of 2 or more substances

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16
Q

in a solution, the ____ is dispersed evenly throughout the ____

A

solute, solvent

17
Q

charge of ΔH for separation of solute particles

A

+ (endothermic)

18
Q

charge of ΔH for the separation of solvent particles

A

+ (endothermic)

19
Q

charge of ΔH for the new interactions between solvent and solute

A
  • (exothermic)
20
Q

charge of ΔS for formation of solution

A

+

21
Q

saturated solution

A

the solvent holds as much solute as possible at that temp

22
Q

unsaturated solution

A

less solute than can dissolve in the solvent at that temp

23
Q

supersaturated solution

A

the solvent holds more solute than is normally possible at that temp

24
Q

polar substances tend to dissolve in

A

polar substances

25
Q

adding nonpolar chains (CH groups) increases _____

A

solubility in nonpolar solvent

26
Q

if a molecule has an OH it is ____

A

polar

27
Q

colligative properties depend on

A

only the number of solute particles

28
Q

solutions of electrolytes should show ______ changes than those of nonelectrolytes

A

greater

29
Q

how is vapor pressure effected by adding solute

A

higher concentrations of nonvolatile solutes make it harder to escape to the vapor phase, lowering vapor pressure

30
Q

how is boiling point effected by adding solute

A

increase boiling point

31
Q

how is freezing point affected by adding solute

A

lowers freezing point

32
Q

ΔT is ____ to find new boiling point and ____ to find new freezing point

A

added, subtracted

33
Q

nonelectrolytes

A

organic molecules

34
Q

osmosis

A

a net movement of solvent from a high area of high solvent concentration (low solute) to low solvent concentration (high solute)

35
Q

osmotic pressure

A

pressure required to stop osmosis

36
Q

colloids

A

suspensions of particles larger than individual ions, but too small to be settled out by gravity