intermolecular forces Flashcards
define intermolecular forces
forces between molecules
what are the three types of intermoleculer forces?
- van der waals forces
- permanent dipole-dipole forces
- hydrogen bonding
how are VDW formed?
electrons are constantly moving around = at nay moment - electrons in the atom are unevenly distributed = the atom has a temporary dipole, which induces another TD in neighbouring molecules
what do VDW do for molecules. give an example
they hold the molecule in a lattice arrangement
-> iodine = the molecules are held together in a molecular lattice by weak vdwf - the atoms are held together by covalent bonds
what two factors affect the strength of VDWF?
molecular size and points of contact
permanent dipole forces
- difference in electronegativity between the charges = forms these forces
what is hydrogen bonding?
it’s the strongest intermolecular force and only occurs if hydrogen is covalently bonded to fluorine, oxygen and nitrogen
why do bonds become polarised in hydrogen bonding
because F,N AND O are very electronegative -they raw the bonding electrons away from the hydrogen atom, so it becomes more positively charged = increasing the difference in electronegatively