Intermolecular forces Flashcards

1
Q

What are intermolecular forces?

A

Forces occurring between molecules

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2
Q

Where do intermolecular forces only occur in?

A

Simple covalent substances

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3
Q

What are the bonds called that hold together atoms by a shared pair of electrons?

A

Covalent bonds

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4
Q

What are the 3 types of intermolecular forces?

A

Induced dipole dipole
Permanent dipole dipole
Hydrogen bonding

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5
Q

Are induced dipole dipole forces temporary or permanent?

A

Temporary

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6
Q

What type of molecules do induced dipole dipole forces occur between?

A

All molecules

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7
Q

Why do induced dipole dipole forces act for a short time?

A

Electron density is constantly changing

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8
Q

Are induced dipole dipole forces strong or weak?

A

Weakest type of intermolecular force

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9
Q

What type of forces interact through symmetrical molecules/non-polar molecules?

A

Induced dipole dipole interactions

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10
Q

Why does the boiling point increase when there are induced dipole dipole forces?

A

More energy is needed to disrupt the forces between the molecules

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11
Q

How do induce dipole dipole interactions arise?

A

Electrons in a molecule are constantly moving
Electron distribution may be unsymmetrical at any one instant
produces a temporary dipole in that molecule
if another molecule approaches the molecule with the c5::temporary dipole, an opposite dipole is induced into the neighbouring molecule

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12
Q

What two factors increase the strength of induced dipole dipole interactions?

A

Increase in the number of electrons in the molecule or atom
Increase in the surface contact of the molecules or atoms

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13
Q

What are polar bonds?

A

Covalent bond between atoms with different electronegativity

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14
Q

What is definition of electronegativity?

A

The ability of an atom to attract the bonding electrons in a covalent bond

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15
Q

what results in the differences in electronegativity?

A

A dipole is the separation of charge in a bond which occurs

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16
Q

When does electronegativity increase?

A

Across a period

17
Q

When does electronegativity decrease?

A

Down a group

18
Q

What element has the highest electronegativity?

A

Fluorine

19
Q

What element has the lowest electronegativity?

A

Francium

20
Q

What are polar molecules?

A

Unsymmetrical molecules whose dipole don’t cancel out

21
Q

Where do electrostatic forces of attraction act between in polar molecules?

A

Opposite charges of the neighbouring molecules

22
Q

What will happen to the overall permanent dipole if the molecule is symmetrical?

A

Dipoles will cancel each other out
There will be no overall permanent dipole
Molecule is now non-polar

23
Q

Do symmetrical molecules have any lone pairs on the central atom?

A

No

24
Q

Are all the atoms around the central atom the same or different in symmetrical molecules?

A

Same

25
Q

What happens when dipoles cancel out in a symmetrical molecule?

A

Molecule has no overall dipole

26
Q

In the central atom of an unsymmetrical molecule, how many atoms are attached to it?

A

2 or more different atoms

27
Q

Do unsymmetrical molecules have any lone pairs on the central atom?

A

Yes
1 or more lone pairs

28
Q

What happens when the dipole do not cancel each other out in an unsymmetrical molecule?

A

It has an overall dipole

29
Q

What is the definition of hydrogen bonding?

A

Intermolecular force between the lone pair of a N, O or F of an NH, OH, or FH with the H atom of NH, OH or FH in a neighbouring molecule

30
Q

What are the 3 most electronegative atoms?

A

Nitrogen
Oxygen
Fluorine

31
Q

Because of the large difference in electronegativity between a hydrogen atom & either an N, O or F atom, what is formed?

A

Very polar bonds are formed

32
Q

Does hydrogen have a strong partial charge (δᐩ)?

A

Yes

33
Q

Give the order of strength of intermolecular forces

A

Hydrogen bonding
Permanent dipole dipole
Induced dipole dipole