intermolecular forces Flashcards

1
Q

What are the types of intermolecular forces

A

-Van der Waals forces
-Permanent dipole-dipole forces
-Hydrogen forces

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2
Q

what is a dipole

A

-The presence of a dipole means that the molecule has a partially positive end and a partially negative end.

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3
Q

Details of Van der Waals forces

A

-These are present in all molecular substances.

-They occur because the electrons are constantly moving around and there will be an uneven electron distribution at any given moment in time.
This causes a temporary dipole within a molecule.

-This temporary dipole induces a temporary dipole in a neighbouring molecule. There is then an attraction between these molecules - this is a temporary induced dipole-dipole attraction.

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4
Q

What affects the Van der Waals forces

A

-The bigger the molecule (the more electrons) the greater the Van der Waals force

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5
Q

What is the order of strength of intermolecular forces

A

-Hydrogen bonding >dipole-dipole>Van der Waals

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6
Q

Details of permanent dipole-dipole

A

-Permanent dipole-dipole attraction between POLAR molecules (eg HCl)

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7
Q

Details of hydrogen bonding

A

-H atom bonded to a very electronegative atom : F,O,N

-The polar bond between the H and N/O/F leaves the H nucleus exposed as H only has one electron.

-Therefore there is a strong attraction from the lone pair on the N/O/F of one molecule to the exposed H nucleus of another molecule.

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8
Q

what are example of H bonding

A

H2O, NH3, alcohols, carboxylic acids, amines,amino acids.

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9
Q

how to tell if a molecule is polar

A

-There are different terminal atoms
or
-Lone pairs arose central atom

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