intermolecular forces Flashcards
What are the types of intermolecular forces
-Van der Waals forces
-Permanent dipole-dipole forces
-Hydrogen forces
what is a dipole
-The presence of a dipole means that the molecule has a partially positive end and a partially negative end.
Details of Van der Waals forces
-These are present in all molecular substances.
-They occur because the electrons are constantly moving around and there will be an uneven electron distribution at any given moment in time.
This causes a temporary dipole within a molecule.
-This temporary dipole induces a temporary dipole in a neighbouring molecule. There is then an attraction between these molecules - this is a temporary induced dipole-dipole attraction.
What affects the Van der Waals forces
-The bigger the molecule (the more electrons) the greater the Van der Waals force
What is the order of strength of intermolecular forces
-Hydrogen bonding >dipole-dipole>Van der Waals
Details of permanent dipole-dipole
-Permanent dipole-dipole attraction between POLAR molecules (eg HCl)
Details of hydrogen bonding
-H atom bonded to a very electronegative atom : F,O,N
-The polar bond between the H and N/O/F leaves the H nucleus exposed as H only has one electron.
-Therefore there is a strong attraction from the lone pair on the N/O/F of one molecule to the exposed H nucleus of another molecule.
what are example of H bonding
H2O, NH3, alcohols, carboxylic acids, amines,amino acids.
how to tell if a molecule is polar
-There are different terminal atoms
or
-Lone pairs arose central atom