inorganic-enthalpy of formation Flashcards
standard enthalpy of formation is
the enthalpy change when one mole of a substance is formed from its elements in their standard state
the 3 standard states are
1-atmosphere pressure
1 mol l^-1 concentration
298k(25 degrees)
entropy of a system is a
measure of the disorder present, the greater the entropy the greater the disorder
entropy increases when
the temperature rises
substance melts, boils or dissolve(solids have low entropy and gases have high entropy)
the second law of thermodynamics states
that the entropy of a reaction system and its surroundings increases for a spontaneous process.
The third law of thermodynamics states
that the entropy of a perfect crystal at 0K is zero
for a reaction to be feasible it has to
have a negative change in free energy between reactants and products.
a reaction can not go faster than the
slowest step in the mechanisms. this is called the rate-determining step