inorganic-enthalpy of formation Flashcards

1
Q

standard enthalpy of formation is

A

the enthalpy change when one mole of a substance is formed from its elements in their standard state

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2
Q

the 3 standard states are

A

1-atmosphere pressure
1 mol l^-1 concentration
298k(25 degrees)

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3
Q

entropy of a system is a

A

measure of the disorder present, the greater the entropy the greater the disorder

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4
Q

entropy increases when

A

the temperature rises
substance melts, boils or dissolve(solids have low entropy and gases have high entropy)

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5
Q

the second law of thermodynamics states

A

that the entropy of a reaction system and its surroundings increases for a spontaneous process.

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6
Q

The third law of thermodynamics states

A

that the entropy of a perfect crystal at 0K is zero

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7
Q

for a reaction to be feasible it has to

A

have a negative change in free energy between reactants and products.

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8
Q

a reaction can not go faster than the

A

slowest step in the mechanisms. this is called the rate-determining step

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