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INORG CHEM Flashcards

1
Q

Who group/arranged the elements based on TRIADS?

A

JW DOBEREINER

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2
Q

Group/arranged the elements based on PERIODS? (octaves)?

A

JOHN NEWLANDS

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3
Q

Father of Modern Periodic Table

A

DMITRI MENDELEEV

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4
Q

Group/arranged elements based on ATOMIC MASS/WEIGHT

A

DMITRI MENDELEEV & MAYER

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5
Q

Created the Modern Periodic Table

A

HENRY MOSELY

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6
Q

States that every 8th element have the same physiochemical properties when arrange according to incr. atomic weight

A

LAW OF OCTAVES

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7
Q

Rule wherein elements with less than 8 e- react to achieve 8 e- to be stable

A

OCTET RULE

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8
Q

Most abundant element? (nonmetal)

A

OXYGEN

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9
Q

Second most abundant element (nonmetal)

A

SILICON

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10
Q

MOST ABUNDANT GAS AIR

A

NITROGEN

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11
Q

Most abundant noble gas

A

ARGON

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12
Q

Most important physiological buffer system? (in our blood)

A

BICARBONATE - CARBONIC ACID

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13
Q

What does it mean if you have high CO2 levels?

A

RESPIRATORY ACIDOSIS

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14
Q

What does it mean when you have low HCO3 level?

A

METABOLIC ACIDOSIS

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15
Q

DOC FOR METABOLIC ACIDOSIS

A

SODIUM BICARBONATE/BAKING SODA

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16
Q

What increases vit e absorption?

A

SELENIUM

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17
Q

Also known as BLUWE VITRIOL

A

CuSO4 Cupric sulfate

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18
Q

What color of container do we store Mg(OH)2?

A

Blue bottle

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19
Q

How do we store Lithium?

A

Coated w/ petroleum or under oil

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20
Q

GLASS TYPES

A

1 - highly resistant borosilicate
2 - treated soda lime glass
3 - soda lime glass
4 - gen. soda lime glass (np)

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21
Q

SORPTION

A

Contents of pharmaceutical products adhere to the glass

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22
Q

LEACH TESTS

A

WATER ATTACK TEST type 2

POWDER GLASS TEST type 1 & 3

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23
Q

DECR. COEFFICIENT OF EXPANSION

A

BORON (as borate)

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24
Q

INCR. REFRACTIVE INDEX

A

Pb

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25
Q

LITHIUM deficiencies

A
  • Hypokalemia
  • Hyponatremia
  • Hypothyroidism
  • Pregnancy probs (Ebstein’s anomaly)
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26
Q

Antidote for Hyperkalemia by potassium

A

(Kayexalate) Sodium polysterene sulfonate

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27
Q

Copper toxicity

A

Wilson’s disease (brown like skin)

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28
Q

Antidote for Copper

A

Penicillamine (Cuprimine)

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29
Q

Toxicity of Silver

A

Argyria (darkened skin)

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30
Q

Antidote for Silver toxicity

A

Sodium chloride/NSS

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31
Q

What causes dermatitis and glossitis?

A

GOLD Au

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32
Q

Antidote for Au poisoning

A

BAL

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33
Q

Calcium toxicity antidote

A

EDTA

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34
Q

Barium toxicity

A

BARITOSIS

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35
Q

Baritosis antidote

A

MgSO4

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36
Q

Zinc toxicity

A

Parakeratosis

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37
Q

Antidote for Zn that caused metabolic acidosis

A

Sodium carbonate

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38
Q

Cadmium toxicity

A

Itai-itai disease

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39
Q

Cadmium toxicity antidote

A

Ca EDTA

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40
Q

Mercury toxicities

A
  • Minamata disease
  • Pink disease
  • Mad hatter’s disease
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41
Q

Mercury poisoning antidotes

A
  • Na formaldehyde sulfoxylate
  • DMSA (succimer)
  • Penicillamine
  • Ca EDTA
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42
Q

Boric acid toxicity

A

Boiled lobster appearance

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43
Q

Aluminum toxicity

A
  • Shaver’s disease/bauxite pneumoconiosis
  • Constipation
  • Alzheimer’s
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44
Q

Silicon toxicity and its antidote

A

Silicosis

Alumina

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45
Q

Pb toxicity and its antidote

A

Plumbism/saturnism

Ca EDTA / Ca versenate

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46
Q

Phosphorus toxicity

A

Acute: garlic odor, luminous vomitous, GI irritation
Chronic: bony necrosis “phossy jaw”

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47
Q

Phosphorus toxicity antidote

A

CuSO4 / ceric sulfate

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48
Q

Causes aldrich mee’s line, garlic breath odor, luminous vomitus, hair loss, severe GI irritation

Ax. BAL/Dimercaprol

A

Arsenic

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49
Q

Causes green tongue

A

VANADIUM

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50
Q

Selenium deficiency

A

Keshan disease

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51
Q

Dental & skeletal fluorosis

A

FLUORINE

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52
Q

Antidote for BROMINE TOXICITY (brominism)

A

Na/NH4Cl Sodium/Ammonium chloride

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53
Q

Iodine deficiency

A

simple or colloid goiter

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54
Q

IODINE TOXICITY ANTIDOTE

A

Starch soln, Na thiosulfate, NaCl

55
Q

Cobalt toxicity

A

Megaloblactic/macrocytic anemia

56
Q

UNIVERSAL ANTIDOTE

57
Q

Emergency tx for Hypercalcemia (IV)

S/E: hypocalcemia rapidly develops

A

Disodium EDTA

58
Q

CYANIDE ANTIDOTE KIT COMPONENT

A

Amyl nitrite + Na nitrite + Na thiosulfate

59
Q

Other agents used in CN poisoning:

A

Methylene blue

Hydroxocobalamin

60
Q

Radiopharmaceutical for liver imaging & potent studied

A

Tc99m phytate

61
Q

Radiopharmaceutical for hepato biliary studies

62
Q

Na iodohippurate

A

diagnosis of liver function

63
Q

Tc99m heptagluconate

A

Kidney imaging & renal function determination

64
Q

Radiopharmaceutical for myocardial perfusion agen

A

Tc99m sestamibi/methoxy isobutyl isonitrite

65
Q

Tc99m pertechnetate

A

Thyroid scanning

66
Q

Tc99m etidronate/phosphonates

A

bone imaging

67
Q

Radiopharmaceutical for lung scanning

A

Tc99m macroaggregated albumin

68
Q

Se75 selenomethionine

A

Dx of pancreatic tumors

69
Q

PEWTER ALLOY COMPOSITION

A

20% Pb 80% Sn

70
Q

BABBIT ALLOY COMPOSITION

A

20% Sb 80% Sn

71
Q

TYPE METAL ALLOY COMPOSITION

A

50% Pb, 25% Sn, 25% Sb

72
Q

ROSE METAL ALLOY COMPOSITION

A

25% Pb, 25% Sn, 50% Bi

73
Q

Most reactive group in the periodic table (seldom found free in nature)

74
Q

Lightest element 1g/mol

75
Q

ISOTOPES OF HYDROGEN

A

Protium - mot abundant
Deuterium - heavy
Tritium - radioactive

76
Q

INDUSTRIAL USES OF HYDROGEN

A 
Haber process (NH3 formation
Oil hydrogenation (margarine production
Gas carrier
77
Q

Lightest metal

78
Q

DOC FOR MANIA OR BPD

79
Q

1st element discovered by use of spectrometer

80
Q

Spirit of hartshorn

A

Strong ammonia soln/water

81
Q

Spirit of sal volatile

A

Aromatic ammonia spirit

82
Q

9.5-10.5% NH3 for neutralizing insects/jelly stings

A

Dilute ammonia soln

83
Q

Only reddish metal

84
Q

Element which is has oligodynamic/germicidal action

85
Q

7.5-8.5% ENT germicide

A

Strong Ag proteinate/Protargol

86
Q

Other name for Colloidal AgCl

87
Q

Used to dissolve GOLD

A

Aqua regia

Selenic acid

88
Q

Colloidal gold w/ stannic

A

Purple of cassius

89
Q

MOST TOXIC METAL

90
Q

Lightest of all structurally important metals

91
Q

A GRIGNARD RGT

92
Q

SOURCES OF MAGNESIUM

A

Mg silicate
Mg carbonate
Mg silicate

93
Q

SOURCES OF CALCIUM

A 
Apatite
Fluorite
Phosphate rock
Dolomite
Gypsum
94
Q

Uses of CALCIUM

A

Muscle contractant
Blood coagulation factor
Release of neurotransmitter

95
Q

PROCESSES THAT CALCIUM UNDERGO AND ITS PRODUCT

A
  • Calcination (by heat ) > LIME CaO
  • Slaking (addition of H2O) > slaked lime
  • Carbonation (addition of CO2) > CaCO3
96
Q

SOURCE OF MERCURY

A

Cinnabar (Aethrop’s mineral)

97
Q

USES OF MERCURY

A
  • Antiseptic
  • Antisyphilitic
  • Parasiciticide
  • Fungicide
  • Diuretic
  • Cathartic
98
Q

SOURCE OF ALUMINUM

99
Q

USES OF ALUMINUM

A
  • Astringent

- Antiperspirant; deo

100
Q

Metal that is solid @ room temp and melts near body temp @ 30°C

101
Q

Green twigs; ant poison

102
Q

2 ALLOTROPES OF CARBON

A 
Crystalline
 - Diamond (purest native form of uncombined carbon; hardest mineral known)
 - Graphite
Amoprhous
 - Butuminous (soft coal)
 - Anthracite (hard coal)
 - Coke (impure carbon)
103
Q

St. Elmo’s fire; light carrier; essential constituent of protoplasm, nervous tissues, and bones

104
Q

3 ALLOTROPIC FORMS OF PHOSPORUS

A
  • White/ Yellow P
  • Red/ Violet P
  • Black P
105
Q

First anti-syphilis; discovered by Paul Erhrlich

A

Arsephenamine; Salvarsan, Compound 606, Magic bullet

106
Q

Cupric acetoarsenite

Rodenticide; insecticide; pigment; blue colarant for fireworks

A

Paris green

107
Q

Cupric hydrogen arsenite

A

Scheele’s green

108
Q

1% Potassium arsenite soln (Fowler’s soln)

A

Former antileukemic

109
Q

Arsenic (III) iodide soln (Donovan;s soln)

A

For trypanosome infxn, malaria, TB, RA, diabetes (before)

110
Q

FATHER OF CHEMOTHERAPY

A

Paul Ehrlich

111
Q

Used as an astringent, antiseptic; internal protectant (antacid + inhibits H. pylori)

112
Q

Insulin mimetic effect

Green tongue

113
Q

3 ALLOTROPES OF OXYGEN

A

Nascent
Atmospheric/molecular O2
Ozone O3

114
Q

SOURCES OF SULFUR

A

Crude furnace

Calcarone (by Frasch process)

115
Q

ALLOTROPES OF SULFUR

A

Alpha/Rhombic S - stable @ room temp

Beta/Monoclinic S - at equilibrium at 96°C

116
Q

SULFUR VARIETIES

A 
Amorphous S
Liquid S
Plastic S
Precipitated S (milk of sulfur)
Sublimed S (flowers of sulfur)
Washed S
117
Q

WHITE LOTION COMPONENTS

A

Sulfurated potash + ZnSO4

118
Q

First radioactive element

119
Q

A super halogen (Linus Pauling); most electronegative element; strongest OA; suppresive effect on thyroid

120
Q

Dephlogisticated muriatic acid

121
Q

DIFF. PREPS OF BROMINE

A 
Bromine TS (1% Br water)
Bromine VS ().1N Br/Koppescharr's soln)
3 Bromide elixirs - Na, K, NH4
122
Q

Heaviest nonmetal

123
Q

IODINE PREP with 2%I2 in water + NaI

A

Iodine soln

124
Q

5% I2 in water + KI

A

Strong iodine/Lugol’s soln

125
Q

1st element produced artificially

A

TECHNICIUM

126
Q

2ND LIGHTEST GAS

127
Q

Niton; synthetic noble cas; Tx. for Cervical CA

128
Q

COMMON ORES OF IRON:

A
  • Hematite
  • Pyrite/”fool’s gold”
  • Iron stone
129
Q

Best known hypothesis of Fe ABSORPTION (duodenum)

A

MUCOSAL BLOCK POSTULATION BY HAHN

130
Q

IRON FORMS

A
  • Cast/pig iron 92-94%
  • Wrought iron - 99.9%
  • Cementite/white cast iron
  • Gray cast iron/graphite scales
131
Q

Heaviest/densest metal

132
Q

Noble metal;cisplatin

133
Q

Present in permanent magnets; Vit B12; enhances beer foam

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