Industrial cracking Flashcards
What is cracking?
Large fractions of crude oil is broken down into smaller fractions by breaking covalent bonds.
Explain why oil companies need to crack “heavy fractions”?
Smaller chain molecules are in higher demand
What are the two types of cracking?
Thermal and Catalytic.
Both involve breaking of C-C bonds to form smaller molecules.
What happens in thermal cracking?
The bonds are broken using a high temperature (700-1200K) and a high pressure (7000kPa).
The alkanes are kept in these conditions for around 1 second.
State the type of cracking that produce a high percentage of alkenes and give 2 conditions.
Name: Thermal cracking
Conditions: High temp + High pressure
What does thermal cracking always produce?
-One small alkane molecules
-Two or more alkene molecules
Any of the c-c bonds in the chain could break
What happens in catalytic cracking?
The bonds are broken using a high temperature (720K) which is lower than in thermal cracking, slight pressure (slightly greater than 1 atmosphere and a zeolite catalyst
Which type of cracking produces a high percentage of branches alkanes and cycloalkanes?
Catalytic cracking
What does catalytic cracking produce?
Cycloalkanes which can be used in motor fuels and aromatic hydrocarbons like benzene.
Branched Alkanes