impression materials and amalgam Flashcards
broad ideal properties
pt comfort operator convenience accuracy removal and undercuts storage compatible with cast material
pt comfort
non-toxic, non-irritant acceptable taste and smell - gagging could distort setting time short removal without damage to tissues
operator convenience
easy to mix and use, quick
setting and mixing time
storage
decontaminable
accuracy
viscosity and contact angle/wettability - surface interaction
setting dimensional changes
elastic recovery
surface detail/reproduction
removal and undercuts
tear strength
rigidity
no effect on oral tissues
storage
dimensional stability
setting shrinkage
thermal expansion/contraction
alginate composition
salt of alginic acid e.g. Na/K alginate 12%
calcium sulphate 12%
trisodium phosphate 2%
filler 70%
modifiers, flavourings, chemical indicators small %
salt of alginic acid
e.g Na/K alginate
12%
reacts with Ca ions
water soluble salt
calcium sulphate
12%
provides Ca ions
reacts to form insoluble gel
trisodium phosphate
2%
delays gel formation - retarder
filler
70%
cohesion, strength
modifiers, flavourings, chemical indicators
small %
improve surface, taste, pH colour change
alginate setting reaction
Na alginate to Ca alginate
one Ca knocks out 2 Na
can’t be broken, irreversible
creation of cross-links between polymer chains
alginate pH change setting reaction
11 to 7
alginate delay
alter amount to alter setting times
trisodium phosphate preferentially reacts with Ca ions in CaSO4 until exhausted
alginate manipulation
correct powder to liquid ratio
water 18-24 degrees
perforated tray and adhesive
increased temp speeds up setting
removing alginate impression
sharp pull
elastic recovery, max tear strength
alginate and crosslinking
cross linking continues after apparent set - greater elastic properties ifs you wait for a few mins after tackiness has gone from surface
using large bulk of alginate
permanent distortion and tearing slightly reduced
alginate properties - pt comfort
non-toxic, non-irritant
acceptable taste, smell
setting time ok
alginate operator convenience
relatively easy to use setting time ok storage - avoid moisture - prepare cast asap to avoid dimensional change - syneresis - release of H2O - imbibition - uptake of H2O
alginate accuracy
not as good as elastomers for surface reproduction
setting changes and flow ok
movement - stresses, distortion. Can create stresses if pull before properly set
not 100% elastic recovery
poor tear strength - avoid deep UCs
poor long-term dimensional stability
- moist gauze over impression to reduce distortion during transit time
where can’t non-elastic impression materials be used?
UCs
impression compound
mucocompressive
thermoplastic - no chemical reaction involved
poor dimensional stability
components of impression compound
resins
waxes
plasticisers
fillers
plasticisers in impression compound
reduce brittleness
fillers in impression compound
overcome tackiness
control degree of flow
minimise shrinkage due to thermal contraction
improve rigidity
colloid
2 phase system of fine particles (1-200nm) of one phase dispersed in another phase
hydrocolloid
if dispersing medium H2O
hydrocolloid 2 states
SOL - viscous liquid state
GEL - jelly-like consistency
- agglomeration of particles
- entangled framework of solid particles enclosing liquid by capillary forces
2 major categories for assessing
material characteristics
clinical performance
- pt acceptance, ease of use
be wary of user feedback
assessing properties
flow/viscosity surface detail/reproduction contact angle/wettability elastic recovery (%) stiffness (flexibility) tear strength mixing and working time (min)
identify properties not mentioned
ISO standards
assess relevant properties of a produce to see whether it meets acceptable requirements for safe and effective use
grooves/indentations of 20/50um are replicated depending on material viscosity
don’t establish best material - designed to exclude unsafe materials from the market
but industries use them as a quality sign
viscosity
ability to flow and make close contact with tissue surfaces
surface wetting
intimate contact with tissue so all of surface is replicated
not form voids due to repulsion or moisture
contact angle
determines how well material envelops the hard/soft tissue surface
low contact angle - spread easily and adapt smoothly
tear strength
stress material will withstand before fracture
reproduction of surface detail
standard notch dimensions
A = 20um
B = 50um (ISO norm)
C = 75um
test whether material fills these notches
rigidity
stress/strain
ideally impression material low rigidity - ease its removal from UC/interdental areas
properties affecting accuracy
viscosity setting mechanism TEC - ideally low to cope with mouth to room temp transition hydrophobic/hydrophillic elasticity tear strength
thixotropy
greater accuracy of impression without excessive flow
become less viscous when subjected to an applied stress
reversible hydrocolloid
agar - no longer used
galactose sulphate, forms a colloid with H2O
better elastic recovery but needs special conditioning unit etc
irreversible hydrocolloid
alginate
alginate process
prep insertion setting removal storage cast prep
polyethers
mod dimensional change on setting
good elastic recovery
allergies
susceptible to moisture absorption
polysulfide rubber
long-term dimensional change - need to pour up quickly good elastic properties good tear strength bad taste messy
condensation-cured silicones
high setting shrinkage
quite rigid
addition-cured silicones
stability quite rigid excellent elastic recovery e.g. Virtual - PVS - tear strength - elastic recovery
viscoelastic behaviour
elastic recovery takes time
- wait before you pour cast - minimise permanent deformation
if load time is less there is less overall permanent strain so lower deformation
- remove imp tray quickly with a sharp pull
fct of impression
produce accurate (dimensional and surface) replica of surface and shape of hard and soft oral tissues