amalgam Flashcards
how is it formed?
by trituration
constituents
Ag 70% Sn 25% Cu 3% Zn 1% Hg 1%
amalgam powder
50% Sn, Ag - intermetallic compound Ag3Sn - y phase Cu - strength and hardness Zn - scavenger (slag) (Hg - pre-amalgamated)
amalgam liquid
50%
Hg - triple distilled
classification
composition
- traditional
- copper enriched
particle shape and size
equation for setting reaction chemical symbols
Ag3Sn + Hg - Ag3Sn + Ag2Hg3 +Sn7Hg9
y
Ag3Sn
y1
Ag2Hg3
y2
Sn7Hg9
equation for setting reaction y
y + Hg - y + y1 + y2
why are there particles of y in the end product?
unreacted particles because insufficient Hg for complete reaction
amalgam matrix
y1 and y2
which is the strongest phase?
y
particle types
spherical/spheroidal
lathe cut
lathe cut
fill ingots
use heat tx to relieve internal stresses
spherical/spheroidal
spray molten metal into inert atmosphere
y2 properties
weak and poor corrosion resistance
effect of higher Hg content
weaker amalgam as will produce more y2
traditional (hand mixed) setting dimensional changes
initial contraction - solution of alloy particles in Hg
expansion - y1 crystallisation
modern (mechanically mixed) setting dimensional changes
small contraction
solid solution of Hg in Ag3Sn
zinc and expansion
saliva/blood: Zn + H20 - ZnO + H2
bubbles - pressure build up - expansion
downward pulpal pain, upward sits proud. Why Zn free
properties depend on:
handling factors - proportioning and trituration - condensation (remove excess Hg) - carving and polishing cavity design product corrosion
factors reducing strength
undermixing too high mercury content after condensation too low condensation pressure slow rate of packing - increments don't bond corrosion creep
amalgam disadvantages
creep - marginal breakdown
thermal properties
doesn’t bond to tooth
aesthetics
amalgam advantages
high abrasion resistance handling ok radiopaque smooth surface if polished short placement time
advantages of spherical particles
less Hg required higher tensile strength higher early compressive strength less sensitive to condensation easier to carve lower setting shrinkage