ceramics Flashcards
ceramic/porcelain
all porcelain is ceramic but not all ceramic is porcelain
difference between decorative and dental ceramics
decorative contain kaolin - clay - hydrated aluminium silicate - opaque dental need to be translucent so kaolin removed - feldspar and silica replace it
dental ceramic constituents
kaolin <5% quartz (silica) 12-25% feldspar 70-80% metal oxides 1% glass up to 15%
decorative ceramic constituents
kaolin 50+% quartz (silica) 15-25% feldspar 15-25% metal oxides <1% glass 0
are ceramics glasses?
yes
feldspar
potash feldspar (KAl silicate)
soda feldspar (Na, Al silicate)
flux - melts and embeds other particles, increases viscosity
lowers the fusion and softening temp of the glass
lowest fusing component and flows during firing forming a solid mass around the other components
borax
lowers fusing temp
metallic oxides
strengtheners
colour to ceramic
chromium
green
cobalt
blue
copper
green
iron
brown
manganese
lavender
nickel
brown
ceramic powder
dentine pink
enamel blue
conventional ceramics - making the powder
heat constituents to >1000 degrees
cool rapidly (fritting) in H2O - creates cracks and crazing of the ceramic mass
mill frit - fine powder
add binder - often starch
conventional ceramics - building up the Rx
powder and distilled water built up
apply to die with brush
different porcelains for E and D
no further chemical reaction required - powder melts together to form crown
- crown heated in a furnace to coalesce the powder into ceramic
heating leads to sintering
what do feldspathic ceramics form when heated to 1150-1500 degrees?
leucite (potassium aluminium silicate)
forms around glass phase
gives powder of known physical and thermal properties
overall properties
aesthetics chemical stability biocompatibility thermal properties dimensional stability mechanical properties
sintering
occurs just above the glass transition temp
when the ceramic particles begin to fuse into a single mass
glass phase softens - coalesce
over time controlled diffusion - form solid ceramic mass
20% contraction - skilled technician to judge contraction in 3D
chemical stability
v stable
generally unaffected by the wide pH range in mouth
don’t take up stain from food/drink
biocompatibility
good
minimal adverse effects on biological tissues
thermal properties
similar to tooth TEC similar to dentine - low stresses to Rx in mouth during use thermal diffusivity low - protective of remaining tooth
aesthetics
best of any Rx material colour stable v smooth surface retain surface better - less staining long-term optical properties - reflectance - translucency - opacity - transparency - opalescence
dimensional stability
once fully fired v stable
during fabrication - shrinkage - must be accommodated for by technician
- 20% normal for a conventional feldspathic ceramic crown
compressive strength
high
hardness
too high
can lead to abrasion of opposing teeth esp if not glazed
tensile strength
v low
flexural strength
v low
fracture toughness
v low
result of mechanical properties
lead to failure during loading
static fatigue
cracking over time, but over v long period and less than you would get from hydrolysis of composite
time dependent decrease in strength even in the absence of any applied load
probably due to hydrolysis of Si-O group within material, over time in an aq env
surface microcracks
during manufacture, finishing or due to occlusal wear
areas where fractures can initiate