Imp. reactions in foods Flashcards
hydrogenation
This is the process of adding hydrogen to unsaturated molecules and making them saturated converting them from a liquid state to a solid or semi-solid state. Depending upon the number of double bonds you want to remove from a molecule you can stop the reaction at particular steps in the process.
interesterfication
The addition of palmitic acid and heat to break off fatty acid chains add them to a pot mix them together and then apply them to multiple fatty acids generating a random orientations, to eliminate the number of identical ones. This ensures that they are seperated so that fats are softer.
intraesterfication
this the process of cutting out fatty acid chains mixing them up and adding them to the same fatty acid.
hydrolysis
this is the process of lipase acid working with water to break off fatty acids in lipids to produce foul odors.
1. productive
2.
saponification
destructive-soap is produced through reaction of fatty acid with metal»soapy flavor
productive-
1. can be used to eliminate fatty acids
2. can be used to identify if they are any impurities in a sample» identifying compounds that did not become soap in all fatty acid solution.
three possible types of hydrogenation reactions
- add enough nickel and h2 to a compound, the nickel will bind to the double bonded carbon producing radicals while hydrogen will bind to the carbon lone paired electrons
- low h2 and low nickel: a single ni atom will bind to the carbon and h atom to the other. Two electrons will be left over on both carbon atoms and a double bond will be reformed this time in a trans isomer fashion.
- Low h2 and high ni: the ni atoms binds to the carbon atoms, and a single hydrogen binds to one of the carbon atoms while the other remains left over so the lone pair on one of the carbon atoms becomes a double bond on another atom creating a positional isomer.