Identification Tests for Anions Flashcards
Cl WHITE PPT
AgNO3
Cl PPT DISSOLVES
6M NH4OH
Cl PPT REPRECIPITATES
6M HNO3
SCN DEEP BLOODY RED SOL
FeCl3
DEEP BLOODY RED SOL
SCN- + FeCl3
Fe(CN)6-3 TURNBULL’S BLUE (dark green blue)
FeSO4
FERROUS SULFATE
Fe(CN)6-3
MUDDY YELLOW
CuSO4
COPER SULFATE
(dark green blue)
Turnbull’s blue
Fe(CN)6-3 + FeSO4 (ferrous sulfate)
(muddy yellow)
Fe(CN)6-3 + CuSO4 (copper sulfate)
IDENTIFICATION TEST FOR BORATE
H2SO4
95% METHANOL
BO3-3 Δ + conc. H2SO4 + CH3OH
GREEN FLAME
GREEN FLAME
BO3-3 Δ + conc. H2SO4 + CH3OH
CO3-2 + conc. H2SO4
EFFERVESCENCE
CO3-2 + conc. H2SO4
EFFERVESCENCE
ARSENATE IDENT TEST
AMMONIUM MOLYBDATE
AsO4-3 + (NH4)2MoO4 (ammonium molybdate)
WHITE PPT
WHITE PPT
AsO4-3 + (NH4)2MoO4 (ammonium molybdate)
CrO4-2 + Pb(NO3)2 (lead nitrate)
YELLOW PPT
YELLOW PPT
CrO4-2 + Pb(NO3)2 (lead nitrate)
brown ring conjunction:
NO2- (nitrate) + diluted CH3COOH + FeSO4
POSITIVE
brown ring conjunction:
NO2- + conc. H2SO4 + FeSO4
POSITIVE
brown ring conjunction:
NO3- + diluted CH3COOH + FeSO4
POSITIVE
brown ring conjunction:
NO3- + conc. H2SO4 + FeSO4
NEGATIVE
CH3COO- (acetate) + FeCl3
ORANGE SOL
ORANGE SOL
CH3COO- (acetate) + FeCl3
SO4-2 + Pb(NO3)2
WHITE PPT
White ppt (soluble in HNO3)
(dissolves upon heating)
AsO4-3 + (NH4)6 Mo7O24
Vinegar-like odor
CH3COO- + Conc. H2SO4