IBX- Mass Transfer 10-12 Flashcards
Steam distillation is used for separation of high boiling
substances from non-volatile impurities.
volatile impurity from still higher boiling substances.
both (a) and (b).
neither (a) nor (b).
both (a) and (b).
The feed to fractionating column is changed from saturated vapour to saturated liquid. If the separation and reflux ratio remains unchanged, the number of ideal stages will
increase
decrease
remains same
depend on saturated boiling point; may increase or decrease
increase
Rose oil is extracted from rose leaves using __________ distillation.
high pressure
low pressure
extractive
steam
steam
Hypersorption refers to a __________ process.
fixed bed absorption
moving bed absorption
fixed bed adsorption
moving bed adsorption
moving bed adsorption
figure
…
Extraction of coffee from its seed is done by
liquid-liquid extraction.
leaching.
extractive distillation.
steam distillation.
leaching.
In azeotropic mixture, the equilibrium vapour composition is
more than liquid composition.
less than liquid composition.
same as liquid composition.
independent of pressure.
same as liquid composition.
With lapse of time, the overhead composition of light component in case of batch distillation with constant reflux
increases
decreases
remains same
may increase or decrease ; depends on system.
decreases
Lewis number, which is important in problems involving simultaneous heat and mass transfer, is the ratio of
mass diffusivity to momentum diffusivity.
thermal diffusivity to mass diffusivity.
momentum diffusivity to thermal diffusivity.
none of these.
thermal diffusivity to mass diffusivity.
According to the film theory of mass transfer, the mass transfer co-efficient is proportional to (where, D = molecular diffusivity)
D
D^2
D^0.5
1/D
D
Dry bulb temperature of the gas is __________ the wet bulb temperature.
less than
more than
equal to
none of these
more than
Decoction refers to the use of solvent
at ambient temperature
at its boiling point
in its vapor form
none of these
at its boiling point
Flash distillation is suitable for separating the constituents of a binary system, which
form minimum boiling azeotrope.
have very wide boiling points.
have very close boiling points.
form constant boiling azeotrope.
have very wide boiling points.
The ratio of Murphree plate efficiency to point efficiency is 1 in a __________ flow model.
plug
perfectly mixed
both (a) & (b)
neither (a) nor (b)
perfectly mixed
The rough value of diffusion co-efficient of water vapor into air at 25°C may be about __________ cm2/sec.
0.25
2.5
1.25
0.0025
0.25
Flooding in a column results due to
high pressure drop
low pressure drop
low velocity of the liquid
high temperature
high pressure drop
Which of the following gas-liquid contacting devices incurs the least pressure drop for a particular duty ?
Grid tray tower
Perforated tray tower
Wetted wall tower
Bubble cap tower
Wetted wall tower
A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. m-xylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture?
The mixture exhibits an azeotrope at 101.3 kPa.
The composition of the mixture, in percent by volume is: o-xylene 30, p-xylene 60. and m-xylene 10.
The composition of the mixture in mole percent is: o-xylene 30, p-xylene 60 and m-xyoene 10.
The mixture contain optical isomers.
The mixture exhibits an azeotrope at 101.3 kPa.
Unsaturated air (with dry bulb temperature and dew point being 35°C and 18°C respectively) is passed through a water spray chamber maintained at 15°C. The air will be cooled
and humidified.
and dehumidified with increase in wet bulb temperature.
at the same relative humidity.
and dehumidified with decrease in wet bulb temperature.
and dehumidified with decrease in wet bulb temperature.
The process employing desorption of the absorbed solute by a solvent is called
elution
osmosis
reverse osmosis
sublimation
elution
If the overall efficiency and Murphree plate efficiency are equal, then both the equilibrium and operating lines are
straight
parallel
both (a) & (b)
neither (a) nor (b)
both (a) & (b)
Which of the following operations does not involve leaching ?
Dissolving gold from ores.
Dissolving pharmaceutical products from bark or roots.
Dissolving sugar from the cells of the beet.
Removing nicotine from its water solution by kerosene.
Removing nicotine from its water solution by kerosene.
The recovery of pencillin from the acidified fermentation broth is done by
distillation
evaporation
absorption
liquid extraction
liquid extraction
Unit operation involved in the prilling of urea is
evaporation
drying
crystallisation
both (b) and (c)
both (b) and (c)
Molecular seives are porous
alumina.
silica.
synthetic zeolites crystals/metal alumino-silicates.
none of these.
synthetic zeolites crystals/metal alumino-silicates.
Calcium ammonium nitrate (a fertiliser) is dried in a __________ dryer.
rotary
vacuum
tunnel
tray
rotary
A binary mixture of benzene and cyclohexane is separated by
flash vaporisation
extractive distillation
solvent extraction
ordinary distillation
extractive distillation
Component A is diffusing in a medium B. The flux NA relative to a stationary point is equal to the flux due to molecular difusion, if
mass transfer is accompanied by reaction.
diffusion of A is in stagnant medium B.
molecular mean free path is high.
there is equimolar counter diffusion.
There is equimolar counter diffusion.
Cox chart is useful in the design of
distillation column
evaporator
dryer
crystalliser
distillation column
Dew point of an air-water vapor mixture
decreases with decrease in pressure.
at constant humidity & total pressure is fixed.
corresponding to any point on the humidity chart is obtained by projecting a line through this point parallel to the temperature axis and to the saturation curve.
all ‘a’, ‘b’ & ‘c’.
all ‘a’, ‘b’ & ‘c’.
Can a cooling tower cool water below the wet bulb temperature of inlet air ?
yes
no
yes ; but height of cooling tower will be prohibitively high.
yes ; but the air flow rate should be excessively high.
no
The solvent used in liquid-liquid extraction should have __________ less than one.
selectivity
distribution co-efficient
both (a) and (b)
neither (a) nor (b).
neither (a) nor (b).
The suitable evaporator for concentration of foaming liquids is a __________ evaporator.
long tube
short tube
vacuum
falling film
long tube
The ratio of Murphree plate efficiency to point efficiency is always > 1 in a __________ flow model.
plug
perfectly mixed
both (a) & (b)
neither (a) nor (b)
plug
Tea percolation employs
liquid-liquid extraction
leaching
absorption
none of these
leaching
Which of the following assumes constant molal vaporisation and overflow ?
McCabe-Thiele method
Ponchan-Savarit method
Enthalpy concentration method
Plate absorption column
McCabe-Thiele method
Absorption factor, for a fixed degree of absorption from a fixed amount of gas should be
1
> 1
< 1
≤ 1
> 1
Selectivity of the solvent used in solvent extraction should be
1
> 1
< 1
0
> 1
Pick out the wrong statement pertaining to leaching.
Fine solids can not be leached in a Pachuka tank.
Door classifier can be used for leaching of coarse solids.
Vegetable seeds can be leached in either of Bollman extractor, Rotocel or Kennedy extractor.
Very high temperature is not needed for the leaching of sugar beet.
Fine solids can not be leached in a Pachuka tank.
Wet bulb and dry bulb temperatures becomes identical at __________ percent saturation curve.
100
50
78
none of these
100
NSc/NPr is called the
psychrometric ratio
Lewis number
Sherwood number
Stantan number
Lewis number
McCabe-Thiele method
uses molal units for material and energy balance.
uses weight fractions to express liquid and vapour composition.
can use any type of units.
is more accurate than Ponchan-Savarit method.
uses molal units for material and energy balance.
The film penetration model of mass transfer was enunciated by
Gilliland
Toor and Marchello
Stefan
Fick
Toor and Marchello
The most economical range of absorption factor is
0 to 0.5
0 to 3
1.25 to 2
5 to 15
1.25 to 2
Channelling is most severe
in towers packed with stacked packing.
in towers packed randomly with crushed solids.
in dumped packing of regular units.
at very high liquid flow rate.
in towers packed with stacked packing.
Out of two equilibrium curves, first one lies above the diagonal and the second lies below the diagonal in the x-y plot. It means that separation by distillation is
not possible in the second case unless vacuum is applied.
not possible in the second case unless high pressure is applied.
more readily done in the second case compared to first one.
none of these
more readily done in the second case compared to first one.
‘ADDUCTS’ and ‘CLATHRATES’ are used in case of
extractive distillation.
crystallisation.
absorption.
none of these.
crystallisation.
Separation of the isotopes of helium for scientific investigations is done by
reverse osmosis
thermal diffusion
leaching
solvent extraction
thermal diffusion
In case of __________ distillation, a solvent is added to alter the relative volatility of the mixture to be separated.
molecular
azeotropic
extractive
flash.
extractive
Adsorption is an unit operation which generally involves __________ systems.
liquid-solid
gas-solid
fluid-solid
solid-solid
fluid-solid
In a binary system, separation is very efficient, when the relative volatility is
1
> 1
< 1
0.5
> 1
Fenske-Underwood equation used for calculating the minimum number of theoretical plates in distillation column is valid for
constant molal overflow
total reflux
constant relative volatility
all (a), (b) and (c)
all (a), (b) and (c)
The binary diffusivity in gases does not depend upon the
pressure
temperature
nature of the components
none of these
none of these
Berl saddle made of carbon cannot be used for
alkalis
SO2
H2SO4
oxidising atmosphere
oxidising atmosphere
1 kg of a saturated aqueous solution of a highly soluble component A at 60°C is cooled to 25°C. The solubility limits of A are (0.6 kgA/kg water) at 60°C and (0.2 kgA/kg water) at 25°C. The amount in kg of the crystals formed is
0.4
0.25
0.2
0.175
0.2
During drying of a solid, the critical moisture content increases with
decreased drying rate
increased thickness of the solid
increased drying rate
both (b) and (c).
both (b) and (c).
Priming in a distillation column
results from very low gas velocity.
is desirable from point efficiency consideration.
is characterised by the presence of foam throughout the space between trays.
reduces the overall pressure drop.
is characterised by the presence of foam throughout the space between trays.
The commonly used solvent in supercritical extraction is
methyl ethyl ketone.
water.
carbon tetrachloride.
carbon dioxide.
carbon dioxide.
When the liquid over a plate is of uniform concentration, then
Murphree efficiency > point efficiency.
Murphree efficiency < point efficiency.
Murphree efficiency = point efficiency.
Murphree efficiency ≠ point efficiency.
Murphree efficiency = point efficiency.
In saturated gas, the
vapour is in equilibrium with the liquid at the gas temperature.
vapour is in equilibrium with the liquid at the room temperature.
partial pressure of vapour equals the vapour pressure of the liquid at room temperature.
none of these.
vapour is in equilibrium with the liquid at the gas temperature.