How Fast Flashcards

1
Q

What is the definition of rate of reaction?

A

The change in concentration of reactants or products divided by the change in time.

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2
Q

What is rate measured in?

A

moldm⁻³s⁻¹

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3
Q

What is continuous monitoring?

A

Measure decrease in reactants/increase in products at regular intervals

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4
Q

How do you know if something is first order?

A

If the concentration of reactant is directly proportional to the initial rate

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5
Q

How do you know if something is second order?

A

If the concentration of reactants squared is directly proportional to the initial rate

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6
Q

How do you know if something is zero order?

A

If the concentration of reactants has no effect on the initial rate

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7
Q

What is the definition of order?

A

The power to which a reactants concentration is raised to in the rate equation

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8
Q

What is the definition of overall order?

A

Add all the orders together in the rate equation

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9
Q

What is the definition of rate constant?

A

k is the rate constant that links the rate of reaction with the concentration of reactants raised to the powers of their orders in the rate equation

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10
Q

What is the definition of half life?

A

The time taken for the concentration of the reactant to reduce by half.

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11
Q

What is the definition of the rate determining state?

A

The slowest step that affects the rate the most

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12
Q

How do you know if something has a constant half life?

A

Half concentration in the same time every time. First order reaction

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13
Q

What is the initial rate method of investigating reaction rates?

A

Measure decrease in reactants/increase in products at regular intervals, draw a graph, draw a transect at the start, calculate initial rate by doing
change in y/change in x

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14
Q

What ways are there to follow the progress of a reaction in the lab?

A
Change in volume/pressure
pH changes
Change in mass
Formation of a precipitate
Colour changes
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15
Q

How is a constant half-life linked to the rate constant?

A

k= ln (2/half-life)

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16
Q

What is the definition for initial rate of reaction?

A

The instantaneous rate at the start of a reaction when the time = 0.
It can be found by measuring the gradient of a tangent drawn at t = 0 on a concentration time graph

17
Q

What is the collision theory?

A

In order for things to react, they must collide with at least the activation energy and with the correct orientation

18
Q

How does temperature affect rate?

A

Increases the proportion of molecules with energy of at least the activation energy.
Also increase kinetic energy so collisions are more frequent

19
Q

How does pressure/concentration affect rate?

A

More particles in the same space increases likelihood of collisions. More frequent collisions.

20
Q

How does a catalyst affect rate?

A

Provides an alternate pathway of lower activation energy so more particles have at least the activation energy required to react

21
Q

What is the rate equation?

A
Rate = k [a]* X [b]*
* = order
22
Q

Using the Arrhenius equation what represents y in y=mx+c

A

ln k

23
Q

Using the Arrhenius equation what represents m in y=mx+c

A
  • (Ea / R)
24
Q

Using the Arrhenius equation what represents x in y=mx+c

A

1/T

25
Q

Using the Arrhenius equation what represents +c in y=mx+c

A

+ ln A