How far Flashcards

1
Q

How is the equilibrium constant denoted?

A

K

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2
Q

What are the units for concentration?

A

moldm⁻³

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3
Q

What brackets are used in then Kc equation?

A

[square brackets]

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4
Q

How do you work out Kc?

A

Concentration of products / concentration of reactants

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5
Q

How do you work out the power to which a concentration is raised to in the Kc equation?

A

However many moles are in the overall balanced equation

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6
Q

Do you + or X the concentrations of products in the Kc equation?

A

X

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7
Q

Do you + or X the concentrations of reactants in the Kc equation?

A

X

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8
Q

What are the units for Kc if there is one more on the bottom than the top?

A

dm³mol⁻¹

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9
Q

What are the units for Kc if there is one more on the top than the bottom?

A

mol dm⁻³

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10
Q

What are the units for Kc if there is two more on the bottom than the top?

A

dm⁶ mol⁻²

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11
Q

What are the units for Kc if there is two more on the top than the bottom?

A

mol² dm⁻⁶

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12
Q

What is the one thing that affects Kc?

A

Temperature

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13
Q

What happens to the rate of the forward reaction when a reactant is added to a system in equilibrium?

A

The rate of the forward reaction will increase to use up all the added material and restore equilibrium

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14
Q

What happens to the value of K when a reactant is added to a system in equilibrium?

A

It remains the same

Only temperature can change it

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15
Q

What happens to the amount of product produced when a reactant is added to a system in equilibrium?

A

More product is produced

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16
Q

Does the concentration of products and reactants have to be the same for it to be at equilibrium?

A

No as long as the forward reaction is occuring at the same rate as the backwards reaction it is in equilibrium

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17
Q

What does a high value of Kc mean?

A

The position of equilibrium is further to the right

18
Q

What does a catalyst do in a reversible reaction?

A

Speeds up the rate of both the backwards and the forwards reaction. Doesn’t effect position of equilibrium but gets to equilibrium quicker

19
Q

If the forward reaction is endothermic what is the backwards reaction?

A

Exothermic

20
Q

If the forward reaction is exothermic what is the backwards reaction?

A

Endothermic

21
Q

If the system is heated and the forward reaction is endothermic what happens to the rate of the forward and backward reaction?

A

Both increase but the forward reaction increases by more because it is endothermic (+ve, takes in heat)

22
Q

How do you work out concentration?

A

Moles / Volume

23
Q

What isn’t included when working out Kc?

A

Solids or liquids

24
Q

What is the definition of partial pressure?

A

The pressure a gas would if it were on it’s own

Partial pressure = total pressure X mole fraction

25
How do you work out the power to which P is in the Kp equation?
It is the same as the number of moles in the overall balanced equation
26
What is partial pressure measured in?
Pa
27
What are the units for Kp if there are 1 more on the top than the bottom?
Pa
28
What are the units for Kp if there are 2 more on the top than the bottom?
Pa²
29
What are the units for Kp if there are 1 more on the bottom than the top?
Pa⁻¹
30
What are the units for Kp if there are 2 more on the bottom than the top?
Pa⁻²
31
How do you work out the mole fraction of a gas?
Number of moles of that gas / Total number of moles of all the gases
32
How do you work out the partial pressure?
Mole fraction X total pressure
33
How do you work out the total pressure?
Add together all the partial pressures
34
How do you work out Kp?
Partial pressure of products / partial pressure of reactants
35
What is a homogeneous equilibria?
When all reactants and products in a reaction are in the same state.
36
What is a heterogeneous equilibria?
When some reactants and products in a reaction are in different states.
37
What does the sum of the mole fractions equal?
1
38
What is Le Chatelier's principle?
When a system in equilibrium is subjected to an external change, the system readjusts itself to oppose/minimise the effects of the change
39
How does increasing pressure affect the position of equilibrium?
Shifts equilibrium to side with fewer moles of gas
40
How does increasing temperature affect the position of equilibrium?
Shifts equilibrium in endothermic (+ve) direction