High intensity sweeteners Flashcards
miraculin
dipeptide in berries in africa
bland taste, but capacity to make other bitter and sour foods taste sweet
Thaumatin
from ketanafe, high sweet tasting proteins and peptides
stevia
shrub, active component is alcohol set
Aspatame
L-aspartyl-l-phenylalanin methyl ester low cal and high sweetness so insignificant calories 200x sweeter than sucrose not heat stable or acid stable can lead to PKU taste not "clean"
Alitame
L-aspartyl-alaniniamide
2000x sweeter
heat stable
acesulfame K
methyl oxadiazine- dioxide 200 x not metabolized in the body, no cal, excrete through urine unchanged more stable than aspartame q
sucralose
very heat stable
trichloroethane derivative of glucose-fructose
- resistant to digestion and metabolic attack
cyclamates
30 x sweeter than sucrose
heat stable
slow onset of sweetness
* possibly carcinogenic
saccaharines
Na+ or Ca+ salts
300x bitter metallic aftertaste
* carcinogenic possibly
describe the role of antioxidants
They can act as reducing agents, hydrogen-donating antioxidants, singlet oxygen quenchers, and, in some cases, metal chelators. They interfere with the oxidation of lipids and other molecules by rapid donation of a hydrogen atom to radicals.
- conjugated aromatic system to delocalize an unpaired electron, and one or more hydroxyl groups that are prone to donate a hydrogen atom or an electron to a free radical;
double bond at 2:3
flavones
benzene ring at 3 position
isoflavones
-oh at 3
flavonols
no double bond at 2:3
flavonones
-oh at 3, no double bond
flavononols