Halogens Flashcards

1
Q

Explain the trend in reactivity down the halogen group

A

Down the group it become harder to gain electron because larger atoms the increase amount of shielding making it harder for elections to be attracted and gained

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2
Q

What is the equation for bronide ion and chlorine

A

Cl2 +Br- = 2cl- + Br2

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3
Q

chlorine at room temp

A

green gas

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4
Q

bromine at room temp

A

red-brown liquid

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5
Q

iodine at room temp

A

grey solid

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6
Q

chlorine appearance in water solution

A

colourless solution

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7
Q

bromines appearance in water solution

A

orange solution

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8
Q

iodine’s appearance in water solution

A

brown solution

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9
Q

chlorine colour in hydrocarbon solvent

A

colourless solution

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10
Q

colour of bromine in a hydrocarbon solvent

A

orange solution

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11
Q

colour of iodine in hydrocarbon solvent

A

pink solution

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12
Q

what happens to electronegativity down the halogens and why

A

decreases as the atomic radius increases causing outmost electrons to be further away from the nucleus and weaker forces due to increased shielding, decreasing the attraction of electrons to the atom

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13
Q

the equation of the production of HBr with sulfuric acid and physical observation

A

NaBr + H2SO4 = NaHSO4 + HBr

steamy fumes

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14
Q

the equation of the production of brown fumes through the oxidation of Br- using H2SO4

A

2HBr + H2SO4 = Br2 + SO2 + 2H2O

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15
Q

Production of SO2 from Br- reducing H2SO4 and physical observation

A

2HBr + H2SO4 = Br2 + SO2 + 2H2O

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16
Q

pneumonic for the reducing power of I-

A

Silly-steamy fumes
People- purple fumes
Can’t- colourless gas
Sell- Solid (yellow)
Guns-gas (bad egg smell)

17
Q

what product of I- as a reducing agent creates the bad egg smell

A

H2S

18
Q

what product of I- as a reducing agent creates purple fumes

A

I2 (iodine)

19
Q

what product of I- as a reducing agent creates steamy fumes

A

HI

20
Q

equation of production of SO2

A

2I- + H2SO4 + 2H+ = I2 + SO2 + 2H2O

21
Q

what happens to reducing power down the halogens

A

As you go down the group, halide ions get bigger, the larger the atomic radius the easier it is to loose electrons therefor reducing power increases.

21
Q

what is the test for halide ions

A

. add nitric acid (removes any ions that could give a precipitate)
.add silver nitrate ( produces a precipitate for halide ions)
.add ammonia conc and dilute (to see if precipitate redissolves to help distinguish ions)

22
Q

what is the chemical equation for Chloride ions hot

A
22
Q

acid rain equation halide

A
22
Q

bad egg smell halide equation

A
23
Q

HI halide equation

A
24
Q

I2 halide equation

A
25
Q
A