Halogens Flashcards
Explain the trend in reactivity down the halogen group
Down the group it become harder to gain electron because larger atoms the increase amount of shielding making it harder for elections to be attracted and gained
What is the equation for bronide ion and chlorine
Cl2 +Br- = 2cl- + Br2
chlorine at room temp
green gas
bromine at room temp
red-brown liquid
iodine at room temp
grey solid
chlorine appearance in water solution
colourless solution
bromines appearance in water solution
orange solution
iodine’s appearance in water solution
brown solution
chlorine colour in hydrocarbon solvent
colourless solution
colour of bromine in a hydrocarbon solvent
orange solution
colour of iodine in hydrocarbon solvent
pink solution
what happens to electronegativity down the halogens and why
decreases as the atomic radius increases causing outmost electrons to be further away from the nucleus and weaker forces due to increased shielding, decreasing the attraction of electrons to the atom
the equation of the production of HBr with sulfuric acid and physical observation
NaBr + H2SO4 = NaHSO4 + HBr
steamy fumes
the equation of the production of brown fumes through the oxidation of Br- using H2SO4
2HBr + H2SO4 = Br2 + SO2 + 2H2O
Production of SO2 from Br- reducing H2SO4 and physical observation
2HBr + H2SO4 = Br2 + SO2 + 2H2O
pneumonic for the reducing power of I-
Silly-steamy fumes
People- purple fumes
Can’t- colourless gas
Sell- Solid (yellow)
Guns-gas (bad egg smell)
what product of I- as a reducing agent creates the bad egg smell
H2S
what product of I- as a reducing agent creates purple fumes
I2 (iodine)
what product of I- as a reducing agent creates steamy fumes
HI
equation of production of SO2
2I- + H2SO4 + 2H+ = I2 + SO2 + 2H2O
what happens to reducing power down the halogens
As you go down the group, halide ions get bigger, the larger the atomic radius the easier it is to loose electrons therefor reducing power increases.
what is the test for halide ions
. add nitric acid (removes any ions that could give a precipitate)
.add silver nitrate ( produces a precipitate for halide ions)
.add ammonia conc and dilute (to see if precipitate redissolves to help distinguish ions)
what is the chemical equation for Chloride ions hot
acid rain equation halide
bad egg smell halide equation
HI halide equation
I2 halide equation