Halogen Reactions Flashcards
What colour and state is fluorine at under standard conditions?
Pale yellow gas
What colour and state is chlorine at under standard conditions?
Green gas
What colour and state is bromine at under standard conditions?
Red-brown liquid
What colour and state is iodine at under standard conditions?
Grey solid
What’s the equation for silver nitrate reacting with a halide in solution?
Ag^+(Aq) + X^-(aq) —-> AgX(s)
What colour is AgCl precipitate?
White precipitate which dissolves in dilute NH3
What colour is AgBr precipitate?
Cream precipitate which dissolves in conc. NH3
What colour is AgI precipitate?
Yellow precipitate which is insoluble in conc. NH3
What happens to reactivity down group 7?
Halogens become less reactive because atomic radii increase, so…
• outer electrons are further from the nucleus
•more shielding so less attraction to the nucleus
KCl(aq) + Cl2(aq)
- aqueous solution ~ stays colourless, no reaction
* organic solution ~stays colourless, no reaction
KCl(aq) + Br2(aq)
- aqueous solution ~ no reaction, stays yellow
* organic solution ~ no reaction, stays orange
KCl(aq) + I2(aq)
- aqueous solution ~ no reaction, stays orange/brown
* organic solution ~ no reaction stays purple
KBr(aq) + Cl2(aq)
- aqueous solution ~ turns yellow, Br2 displaces
* organic solution ~ turns orange, Br2 displaced
KBr2(aq) + Br2(aq)
- aqueous solution ~ no reaction, stays yellow
* organic solution ~ no reaction, stays orange
KBr2(aq) + I2(aq)
- aqueous solution ~ no reaction, stays orange/brown
* organic solution ~ no reaction stays purple