Groups of the periodic table Flashcards
Classification of Alkali Metals, Halogens, and Noble Gases
Alkali Metals (Group 1):
Located in Group 1 of the periodic table.
Highly reactive metals.
Have one electron in their outer shell.
Examples: Lithium (Li), Sodium (Na), Potassium (K).
Halogens (Group 7):
Located in Group 7 of the periodic table.
Non-metals that exist as diatomic molecules (e.g., Cl₂, Br₂, I₂).
Have seven electrons in their outer shell.
Examples: Chlorine (Cl), Bromine (Br), Iodine (I).
Noble Gases (Group 0):
Located in Group 0 (or Group 18).
Colourless, odourless, and inert gases.
Have a full outer electron shell (stable configuration).
Examples: Helium (He), Neon (Ne), Argon (Ar).
Main Physical Properties of Alkali Metals
Low Density: They are light metals; lithium, sodium, and potassium can float on water.
Soft: Can be cut with a knife.
Shiny: Have a metallic luster when freshly cut.
Low Melting and Boiling Points: These decrease down the group.
Reactions of Lithium, Sodium, and Potassium with Water
Lithium: Fizzes gently, forms lithium hydroxide and hydrogen gas.
Sodium: Reacts more vigorously, forms sodium hydroxide and hydrogen gas, may melt into a ball.
Potassium: Reacts very vigorously, forms potassium hydroxide and hydrogen gas, may ignite with a lilac flame.
Word Equation (for all):
Metal + Water → Metal Hydroxide + Hydrogen
(e.g., Lithium + Water → Lithium Hydroxide + Hydrogen)
Balanced Equations:
Lithium: 2Li (s) + 2H₂O (l) → 2LiOH (aq) + H₂ (g)
Sodium: 2Na (s) + 2H₂O (l) → 2NaOH (aq) + H₂ (g)
Potassium: 2K (s) + 2H₂O (l) → 2KOH (aq) + H₂ (g)
Pattern of Reactivity of Alkali Metals
Reactivity Increases Down the Group: Lithium reacts less vigorously, potassium reacts explosively.
Explanation of Alkali Metals’ Reactivity (Electronic Configuration)
Alkali metals have 1 electron in their outer shell.
As you go down the group, the outer electron is further from the nucleus.
The attraction between the outer electron and the nucleus decreases.
This makes it easier to lose the outer electron, increasing reactivity down the group.
Appearance of Chlorine, Bromine, and Iodine at Room Temperature
Chlorine (Cl₂): Greenish-yellow gas.
Bromine (Br₂): Reddish-brown liquid.
Iodine (I₂): Purple-black solid.
Trends in Colour, Melting Point, and Boiling Point of Halogens
Colour: Becomes darker down the group (Chlorine → Green, Bromine → Red-brown, Iodine → Purple-black).
Melting/Boiling Point: Increases down the group (Chlorine has the lowest, iodine has the highest).
Prediction: A halogen below iodine would likely be a solid with an even higher melting/boiling point and darker colour.
Chemical Test for Chlorine Gas
Chlorine turns damp blue litmus paper red, then bleaches it white.
Trends in Reactions of Halogens with Metals
Reactivity Decreases Down the Group.
More reactive halogens will displace less reactive halogens from solutions of their salts (e.g., chlorine displaces bromine from sodium bromide).
Word and Balanced Chemical Equations for Halogens with Metals
Sodium + Chlorine → Sodium Chloride
Na (s) + ½Cl₂ (g) → NaCl (s)
Magnesium + Bromine → Magnesium Bromide
Mg (s) + Br₂ (g) → MgBr₂ (s)
Hydrogen Halides and Their Properties
Hydrogen Halides: Compounds formed between hydrogen and halogens (e.g., HCl, HBr, HI).
Properties:
Form acidic solutions in water (e.g., HCl forms hydrochloric acid).
HCl is a gas at room temperature but dissolves in water to form hydrochloric acid.
Relative Reactivity of Halogens
Reactivity Decreases Down the Group: Chlorine is more reactive than bromine, which is more reactive than iodine.
Displacement Reactions of Halogens
More reactive halogens displace less reactive halogens from their compounds in solution.
Example:
Chlorine + Potassium Bromide → Potassium Chloride + Bromine
Cl₂ (g) + 2KBr (aq) → 2KCl (aq) + Br₂ (l)
Displacement Reactions as Redox Reactions
Oxidation: The less reactive halogen (e.g., bromine) loses electrons.
Reduction: The more reactive halogen (e.g., chlorine) gains electrons.
Example:
Cl₂ + 2Br⁻ → 2Cl⁻ + Br₂
Ionic Equations for Displacement Reactions of Halogens
Chlorine displacing bromine:
Cl₂ (g) + 2Br⁻ (aq) → 2Cl⁻ (aq) + Br₂ (l)