Group 2 Flashcards
Group 2
Earth alkali metals
Properties (gp2)
Shiny when freshly cut
Tarnish upon exposure to O2
Soft (harder down group)
Low density (increases down gp)
Electrical conductors
Appearance of gp2 metals
Shiny when freshly cut
Tarnish when exposed to o2 as reactive so forms thin oxide layer
Softness (gp2)
Softness increases going down
Weaker metallic bond due to increase in shielding
First ionisation energy going down (gp2)
More shells so atomic radius increases going down
More shielding experienced
So easier to lose electron going down
Metallic bonding
Electrostatic attraction between positive metal ions and negative delocalised electron
Melting point and boiling point (gp2)
Decreases down group
Larger atomic size
distance between positive metal ions and delocalised electrons increases
Lower charge density
Weaker metallic bonding
Reaction w water equation
X(s) + 2H2O(l) -> X(OH)2(aq) +H2 (g)
Reaction w steam equation
X(s) + H2O(g) ~> XO(s) + H2
Trend in reactivity in water (gp2)
Reactivity Increases going down
As atomic size increases
So larger atomic radius
Weaker metallic attraction between positive ion and delocalised electron
Beryllium w water liquid
Little to no reaction
Beryllium w steam
Vigorous heating or reaction w steam
produces white solid (beryllium oxide)
h2 gas bubbles
Mg w cold water
Slow reaction
White ppt
Colourless gas bubbles (h2)
Mg w steam
Burns w white flame
Produces white solid (MgO)
H2 gas bubbles
Calcium w water
Reacts vigorously
Produces white solid that dissolves in water to form clear colourless limewater Ca(OH)2
H2 gas bubbles
Calcium w steam
Vigorous reaction
Bright flame
White solid CaO
H2 bubbles
Using Mg q
MgSO4 test
Prepare sample solution
Add few drops of Barium Hydroxide
Positive test = white ppt forms
Because barium Sulfate is insoluble in water
Test for sulfate ions
Reagent: barium chloride
Adding few drops of HCL
Adding few drops of BaCl2
Positive test: white ppt of barium sulfate forms
Group2 + HCl
Reacts vigorously
Ca + H2SO4
Reactions slowed stopping H bubbles from rising
Group 2 metals
Group 2 sulfate become sulfates become less soluble down group
Barium sulfate use
Insoluble
So used for x ray imaging to view digestive system to show outline of organs