Atomic Structure Flashcards
atoms subatomic particles
protons
neutrons
electrons
charge of proton
+1
mass of a proton
1
charge of a neutron
0
mass of a neutron
1
charge of electron
-1
mass of electron
1/1840
mass number (A)
sum of protons and neutrons in nucleus
atomic number (Z)
number of protons in nucleus
isotope
atoms of the same element that have the same number of protons but different number of neutrons
relative atomic mass definition
weighted average mass of all isotopes of an atom of an element, relative to 1/12th the mass of an atom of carbon-12
relative atomic mass equation
∑(isotopemass × abundance) / totalabundance
max electrons for an energy levels equation
n = 2n^2
orbitals
regions in space where electrons are most likely to be found
ionisation energies
energy to remove one mole of electrons from one mole of atoms in its gaseous phase
ionisation energy changes across a period
ionisation energy increases across (left to right) a period
due to increasing nuclear charge (more protons but same shielding)
which decreases atomic radii
so attraction between negative electron and positive protons increases
so more energy needed to remove one mole of electrons from one mole of atom in gaseous state
ionisation energy changes down group
ionisation energy decreases down group
as atoms get larger
so more shielding (more energy levels)
so weaker attraction between outer electrons and positive nucleus
so less energy is required to remove one mole of electrons form one mole of an atom
Pauli exclusions principle (electron spin)
two electrons in same orbitals must have opposite spins (upspin or downspin)
hunds rule (electrons in orbitals)
electrons will occupy degenerate orbitals (same energy) singly before pairing up to fill one orbital in order to minimise electron pair repulsion
effective nuclear charge
net positive charge experienced by an electron in an atom, considering nuclear charge and sheilding
s orbital
spherical orbital
one s orbital in each energy level
max s orbital can hold up to two electrons
p orbital
dumbbell shaped
three p orbitals in each energy level
max p orbital can hold up to six electrons (3x2)
d orbitals
five d orbitals in each energy level
max 10 electrons (2x5)
f orbitals
seven f orbitals in each energy level
max 14 electrons (2x7)