Atomic Structure Flashcards

1
Q

atoms subatomic particles

A

protons
neutrons
electrons

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2
Q

charge of proton

A

+1

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3
Q

mass of a proton

A

1

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4
Q

charge of a neutron

A

0

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5
Q

mass of a neutron

A

1

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6
Q

charge of electron

A

-1

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7
Q

mass of electron

A

1/1840

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8
Q

mass number (A)

A

sum of protons and neutrons in nucleus

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9
Q

atomic number (Z)

A

number of protons in nucleus

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10
Q

isotope

A

atoms of the same element that have the same number of protons but different number of neutrons

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11
Q

relative atomic mass definition

A

weighted average mass of all isotopes of an atom of an element, relative to 1/12th the mass of an atom of carbon-12

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12
Q

relative atomic mass equation

A

∑(isotopemass × abundance) / totalabundance

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13
Q

max electrons for an energy levels equation

A

n = 2n^2

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14
Q

orbitals

A

regions in space where electrons are most likely to be found

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15
Q

ionisation energies

A

energy to remove one mole of electrons from one mole of atoms in its gaseous phase

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16
Q

ionisation energy changes across a period

A

ionisation energy increases across (left to right) a period
due to increasing nuclear charge (more protons but same shielding)
which decreases atomic radii
so attraction between negative electron and positive protons increases
so more energy needed to remove one mole of electrons from one mole of atom in gaseous state

17
Q

ionisation energy changes down group

A

ionisation energy decreases down group
as atoms get larger
so more shielding (more energy levels)
so weaker attraction between outer electrons and positive nucleus
so less energy is required to remove one mole of electrons form one mole of an atom

18
Q

Pauli exclusions principle (electron spin)

A

two electrons in same orbitals must have opposite spins (upspin or downspin)

19
Q

hunds rule (electrons in orbitals)

A

electrons will occupy degenerate orbitals (same energy) singly before pairing up to fill one orbital in order to minimise electron pair repulsion

20
Q

effective nuclear charge

A

net positive charge experienced by an electron in an atom, considering nuclear charge and sheilding

21
Q

s orbital

A

spherical orbital
one s orbital in each energy level
max s orbital can hold up to two electrons

22
Q

p orbital

A

dumbbell shaped
three p orbitals in each energy level
max p orbital can hold up to six electrons (3x2)

23
Q

d orbitals

A

five d orbitals in each energy level
max 10 electrons (2x5)

24
Q

f orbitals

A

seven f orbitals in each energy level
max 14 electrons (2x7)

25
what element does the s orbitals start
H = 1s
26
what element does p orbitals start
B = 2p
27
what element does d orbitals start
Sc = 3d
28
what element does f orbital start
La = 4f
29
Aufbau principle
electrons fill orbitals starting from lowest energy level to highest
30
first ionisation energy
energy required to remove one mole of electrons from one mole of atoms in the gas phase
31