Giant covalent structures Flashcards
Examples of Giant Covalent Structures
Diamond, silicon and silicon dioxide.
Properties of diamond
- A very hard substance
- Poor electrical conductivity
- Very high melting and boiling point
Properties of silicon
- Poor conductor of electricity
- Electrical conductivity can be improved by a process known as doping, the addition of small amounts of elements such as phosphorus or boron to pure silicon.
Properties of Silicon dioxide (SiO2)
- Very hard substance
- Poor conductor of electricity
- High melting and boiling point
Why do giant covalent structures have such high melting and boiling points?
It takes a lot of energy to break the strong covalent bonds between the atoms.
What are allotropes?
Allotropes are different forms of the same element in the same physical state.
Allotropes of carbon
Graphite, fullerene C60, diamond, graphene
Properties of graphite
- Good electrical conductor
- Soft
Structure and bonding angle of carbon in graphite
each carbon atom is covalently bonding to 3 other carbon atoms in a 120º angle. Graphite has a layered structure consisting of carbon atoms arranged in hexagonal rings. The layers are held together by LDF. Each carbon atom has a pair of delocalised electrons.
What type of structure is fullerene C60?
A simple molecular structure
Graphene properties
- very high tensile strength
- high electrical and thermal conductivity.
Graphene structure
- A single layer of graphite
- Bond angle of 120º, trigonal planar
- carbon atoms in hexagonal rings