Gas Laws and Gas Cylinders Flashcards
Daltons Law
total pressure of a gas is equal to the sum of the pressure of individual gases in a mixture
ambient pressure
pressure of the surrounding (ex gas or liquid)
Alveolar Gas Equation
PAO2 = FiO2 x (Pbarometric-PalveolarH2O) - PaCO2/RQ
RQ
(=VCO2-VO2) .8 reflects 8 CO2 molecules produced for every 10 O2molecules burned. means more O2 leaves alveoli than is returned in the form of CO2 to alveoli.
alveolar arterial oxygen gradient
(A-a)DO2
arterial-alveolar ratio
PaO2/PAO2 ratio. better for high FiO2
can also be PaO2/FiO2. for this way, less than 200 means acute RDS. used to quantify hypoxemia
reasons for (A-a)DO2 difference being normal
regional VA/Q mismatch (largest influence)
anatomic shunt of blood, like thespian circulation or bronchial circulation)
pathological A-a O2 difference reasons
significant VA/Q mismatch
intrapulmonary shunts
Alveolar-cap membrane diffusion block
PFO
henrys law
amount of gas dissolved in liquid is directly proportional to pressure applied to that gas as it overlies the liquid.
Concentration of gas = Pressure of gas/KH
(KH is a constant, solubility of gas in particular solvent. measures likelihood to leave liquid to gaseous state.)
(Pressure of gas is partial pressure of gas above liquid)
Boyles Law
at a constant temperature, pressure of a gas is inversely proportional to volume. increased pressure in decreased volume. related to more collisions in a smaller container.
P1 x V1 = P2 x V2
Charles Law
at a constant pressure, the volume of a gas is directly proportional to its absolute temperature. increased temperature (kelvins) = increased volume.
V1/T1=V2/T2
Boyles and Chalres’ Law Combined
P1V1/T1 = P2V2/T2
Gay-Lussacs Law
at a constant volume, pressure of a gas is directly proportional to absolute temp. increased temperature is increased pressure.
P1/T1=P2/T2
Ideal Gas Law
PV=nRT or V=nRT/P
where R is a constant at 62.36L
how to calculate R for ideal gas law
PV/nT=R where 760mmHgx22.4L/1mole x273k = 62.36L mmHg /mole K