Gas Laws Flashcards
Kinetic Theory of Gases
1) The molecules/atoms that make up a gas have virtually no volume compared to the volume that the gas occupies. (This volume is due to motion of the gas molecules)
2) This motion is constant & random. (direction & speed)
3) All collisions between molecules are perfectly elastic (no loss of motion to other forms of energy).
Gas Laws
Mathematical relationships that describe properties of gases.
Pressure (P)
Force #of collisions
–––––
Area surface area of container
collisions { # particles present
Atmospheric (Atm) Pressure
Collisions from atmospheric gases with the dish of Hg. (Measured by height of Hg)
Standard Pressure (sea level)
760 mmHg
29.92 inHg
1 Atm
101.3 kPa
Water Pressure
10m of water = 1 Atm
Boules Law (1662)
For a fixed mass of gas at constant temp, the pressure & volume of the gas varies indirectly.
P1V1 = P2V2
Charles’ Law (1787)
For a fixed mass of gas at constant pressure, the Kelvin temp & volume of the gas varies directly.
V1 V2
–– = ––
T1 T2
Amonton Guy-Lussac’s Law (1802)
For a fixed mass of gas at constant volume, the Kelvin temp & pressure very directly.
P1 P2
–– = ––
T1 T2
Maldenburg Spheres
The particles of the atm colliding w/ the sphere on the outside & very few collisions on the inside, so the atm pushes the sphere together.
At same pressure: easy to separate b/c the collisions inside = collisions outside.
The Combined Gas Law
- Sealed Container
- Kelvin Temp.
P1V1 P2V2
––––– = –––––
T1 T2
Dalton’s Law of Partial Pressure
The total pressure for a mixture of gases is the sum of the individual pressures at the same conditions (vol & temp).
Σ IndPressure = Σ TotalPressure
Gas over Water (Wet Gas)
PAtmOutside = PDryGas + PH2OVapor
Ideal Gas Law
PV=nRT R is universal gas constant 8.21Atm 8.31kPa 6.24mmHg
Graham’s Law of Diffusion
The movement of gases/liquid/ions (solute) from areas of high concentration toward areas of low concentration until there is a uniform concentration throughout. -Driven by Random Molecular Motion RateA √M. Mass B ––––– = ––––––––––– RateB √M. Mass A