Gas laws Flashcards
Describe the structure of gas particle
Gas particles in a container are spaced out and move randomly, these particles will bump against each other and the container, when they hit the wall pressure is generated
Describe what happens to gas particles when it is heated
Gas particles move faster and more randomly, there are more frequent collisions, generating more pressure, causes pressure to increase as volume of gas decreases
what is total pressure?
the sum of all collision forces exerted, the more collision the greater the pressure
Define Charles’ law
for a fixed mass of gas at constant pressure, the volume is directly proportional to the temperature
Define Boyle’s law
PxV=constant
If pressure increases, volume decreases
For a fixed mass of gas, the product of a volume of gas and pressure are always the same providing temperature is constant
decreasing volume, increases pressure
Boyle’s law equations
PxV=constant
p1v1=p2v2
Define the order of the atmosphere
- troposphere (closest to earth) 0-12km
- stratosphere 12-50km
- mesophere 50-80km
- thermosphere 80-700km
- exosphere 700-10,000km
What occurs to volume of gas during exhalation?
Volume decreases as gas cools as it leaves the body, as volume is proportional to temperature
What is air pressure in atm measured in?
kPa/mmHg (BP)
What is air pressure known as? and what is it at sea level?
Barometric pressure
101kPa
Where is atm pressure the greatest?
it is greatest closest to the earth surface, pressure decreases as altitude rises
Conversion of Kpa to mmHg
1kPa=7.5mmHg
conversion of 1mmHg to kPa
1mmHg=0.133Kpa
e.g., 750mmHg x 0.133=99.75kPa
Define the composistion of air
N=78.0%
O= 20.9%
Ar=0.9%
CO2=0.04%
other gases 0.17%
Define Dalton’s law
The total pressure of a mixture of gases is equal to the sum of the partial pressures that each gas would exert in isolation
Partial pressure calculation
partial pressure= % of gas x atm pressure
Calculate partial pressure of oxygen in atm pressure
20.9x101=21.109kPa
factors affecting movement of gases
Concentration gradient
temperature
solubility of gas in liquid
Define diffusion
the net movement of a group of particles from an area of high concentration to an area of low concentration. Diffusion increases with temp and a steep conc gradient
Partial pressure gas movements
Gases will equalize, from high to low, The speed in which gases move depends on partial pressure difference, the larger the pressure gradient the faster gas particles will travel
Define Henry’s law
This law states that the number of molecules dissolving in a liquid is proportional to the partial pressure at the surface of the gas
Henry’s law equation
P=KH.C
P= partial pressure
Kh= henry’s law constant, dependant on solute, solution and temp
C=concentration of dissolved gas
What occurs to pressure in high altitude
as you ascend air pressure decreases, e.g., pressure at Everest is 33kPa
partial pressure of O2 also decreases
What is partial pressure of O2 at everest
P=20.9x33kpa
=6.897kPa
What is water vapour pressure?
the water vapour pressure is exerted by water molecules in gaseous form
Partial pressure of water equation at body temp (37c)
6.3kPa
Partial pressure of moist inspired oxygen equation
is 20.9x (101-6.3kPa) (atm P)
20.9x94.7=19.8kPa