Galvanic/Fuel Cells Flashcards
Galvanic Cells reactants
Spontaneous redox reactions, fixed reactants chemical -> electrical
Fuel Cells reactants
reactants are not fixed but rather constantly supplied from an external source
Difference between galvanic and fuel cells
Fuel cells have fixed reactants, whilst fuel cells do not have fixed reactants, but rather have reactants that are constantly supplied from an external source
Primary Cell
Irreversible system, once energy is obtained they are disposable
Secondary Cell
Reversible system, once energy is obtained they can be recharged and reused
Why can’t primary cells be recharged?
Products of oxidation and reduction may move away from the electrodes therefore the backward reaction cannot be forced
Side reactions may be occurring with the formed products
Discharge characteristics
Anode is negative, cathode is positive, galvanic cell, spontaneous
Recharge characteristics
Anode is positive, cathode is negative, electrolytic cell, NON-spontaneous
Purpose of an electrolyte in a fuel cell
Allows only the movement of ions through the cell, completing the circuit so redox reaction can occur.
Advantages of a fuel cell
More efficient
H2O produced could be used elsewhere (sustainable greenhouse gas)
Fuel cells emit less Co2 as a byproduct.
Fuel Cell definition
A galvanic cell that converts chemical energy to electrical energy with a constant supply of reactants provided by an external source.