fundamental concept in ORM Flashcards

1
Q

reaction mechanism

A

breaking of old covalent bonds and making of new covalent bond in organic compound

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2
Q

substrate

A

vulnerable to be attacked (present in more amount)

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3
Q

reagent

A

attacking (present in less amount)

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4
Q

Bond breaking

A

homolysis- generate free radicle
heterolysis- generate ion

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5
Q

types of attacking reagent

A

electrophile
neucleophile

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6
Q

electrophile

A

electron deficient
lewis acid
H+, Cl+, CH3+, NO2+
AlCl3, BF3, SO3, FeCl2, AlBr3, AlI3, ZnCl2

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7
Q

neucleophole

A

lewis base
X-, OH-, CN-, RCOO-
NH3, H2O, R3N, R-O-R

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8
Q

More the electronegtivity, less will be the ability to give away electrons

A

CH,-> NH2->OH->F-

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