Fuels and pollution controls Flashcards
What are the different fraction of Crude oil?
Petroleum gas- Heating
Naphtha- Solvents, polymers, fuel
Gasoline- Fuel
Kerosene- Aircraft fuel
Gas oil- Diesel fuel
Lubricating oil- Cooling, motor oil, lubricant
Heavy fuel oil- Industrial fuel
Residuals- Roads
Cracking?
Heating up long chain alkanes to 800C without oxygen to break C-C bonds
What does the Octane rating specify?
The resistance a Hydrocarbon has to auto-ignition
Automotive Fuel Requires?
- Volatility- Too volatile causes vapour lock
- Auto-ignition- In Petrol not wanted as early igition causes knocking. In Diesel wanted.
- Octane rating rates a fuel on this
- Additives- Anti-knock, Lubricants
What is the RON Number?
Research Octane Number
What are the different polutants emitted from cars?
- Carbon Dioxide- Combustion
- Carbon Monoxide- Incomplete Combustion
- NOx SOx Volatile Organic Compounds- Unburnt fuel
- Paritculates- Unburnt fuel
How to reduce polutants from cars?
- Improved fuels
- Engine control
- Lean-burn tech
- Catalytic converters
- Alternative fuels
How do improved fuels reduce polution?
Reduces Sulphur and Aromatics and eliminates Lead
How do Engine control reduce polution?
Ensures complete combustion
How do Lean-burn tech reduce polution?
Operating engines at high air/fuel ratios reduces unburnt fuel and CO as well as improving fuel economy.
Ratio should be 65:1.
How do Catalytic converters reduce polution?
- Converts CO, NOx and VOC’s to safer compounds.
- Uses Platinum, Rhodium and Palladium.
- They work at high temp. and are useless when the engine starts
What are and how do Alternative fuels reduce polution?
- LPG- Less poluting
- Alcohol- Sustainable, High RON, Less polluting, less energy dense, deforestation
- Electric- No polution from the car
- Sustainable Biodiesel- Sustainable, just as polluting as normal, gels at low temps
- Hydrogen fuel cells- Produces water, Hydrogen hard to find
Lubricants Requirements
- Reduce friction
- Stable at operating temp.
- Prevent corrosion and oxidation
- Correct viscosity
- Coat all surfaces
- Environmentally friendly and safe
- Help heat transfer
Composition of Lubricants
Hydrocarbon oils and greases- Mineral Oils
Synthetic lubricants- Silicone grease
Solid lubricants- Graphite, Teflon