Bonding Flashcards
Lewis Symbols
Consists of the element and a dot for each valence electron
What are the 3 types of bonding?
Covalent
Ionic
Metallic
Covalent Bonding
Electron sharing normally between non metals
Non metals tend to do this as their ionisation energies are too high
They are v. strong
Directional bonds- molecules are certain shapes
Can form giant strucures for example diamond
Ionic Bonding
Transfer of electrons between two atoms forming cations and anions to gain stability
Strong electrostatic attraction between oppositely charged ions
Typical properties: High melting and boiling point, brittle
Usually crystalline structure
Not directional
Between Ionic and Covalent bonding
In many cases Ionic and Covalent are not suitable. The bond has mixed character. (HCl)
Creates polar molecules
Electronegavity difference needs to be 0.4-2 for this to be the case
Electronegativity
The power of an atom to withdraw electrons from the other atom in a bond
3 Types of Secondary Bonding
Polar Bonds
Hydrogen Bonding
VDW Forces
Polar Bonds
Originate from the imbalance of charge between atoms in a molecule.
This reults in an attractive force between molecules
Dipole-dipole interactions
Hydrogen Bonding
Same as polar bonding and is used when one of the polar atoms is Hydrogen
It give Water its high boiling point, as Water has two pairs of none bonding valence electrons
Hydrogen bonding is stronger than most intermolecular forces
VDW’s forces
V. weak forces
At a particular time electrons are not even distributed, giving a molecule an inbalance in charge
After a short time, this induces this in other molecules and gives a net attraction
Secondary bonding affects
Boiling/Melting point- The stronger the secondary bond, the higher the temp.
Surface tension- Results from the cohesive intermolecular forces in a liquid
Capillary action- the ability of a liquid to flow in narrow spaces without thhe assistance of external forces
Vapor Pressure- Pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases
Miscibility- the property of a substance to mix in all proportions to form a homogeneous solution
Secondary Bonding strength
Ion-Dipole H Bond Dipole-dipole Ion-induced dipole Dipole induced dipole VDW's