Fuels 2 Flashcards
An important primary liquid fuel.
Petroleum
It is a dark colored viscous oil found deep in the earth’s crust.
Petroleum
It is believed to have been formed millions of years ago by anaerobic decay of marine plant and animal life under the influence of high temperature and pressure.
Petroleum
It is mainly a complex mixture of hydrocarbons (like straight-chain paraffins, cycloparaffins, olefins and aromatics) with small amounts of other organic compounds containing N, O and S, and traces of inorganic compounds.
Petroleum
The average composition of_____ is C: 83 - 87%; H: 11 - 15 %; S, N and O: 0.1- 5%.
Crude oil
“It is the process of separation of crude oil into different useful fractions on the basis of their boiling points”
Petroleum refining
The volatile components condense on the upper plates of the fractionating column while the less volatile fraction is collected on the lower plates.
Petroleum refining
is a major fraction of petroleum refining. It is converted to petrol by cracking.
Heavy Oil
Heavy oil is a major fraction of
petroleum refining
It is converted to petrol by cracking.
Petroleum
The objective of ______is to obtain greater yields of improved gasoline by thermal decomposition of the surplus heavier fractions.
cracking
Gasoline obtained by______ gives better engine performance
cracking
the knocking sound often occurs when
fuel and air mixture is incorrect
the knocking sound often occurs when the fuel and air mixture is incorrect, which causes the fuel in uneven pockets rather than uniform burst. If left untreated, it can cause damage to the piston and cylinder wall
less knocking
causes the fuel in uneven pockets rather than uniform burst.
fuel and air incorrect mixture
Gasoline obtained by cracking gives better engine performance than
straight-run gasoline
obtained from fractional distillation of crude oil
straight-run gasoline
defined as the process of decomposition of higher molecular weight hydrocarbons (higher boiling) into lower molecular weight hydrocarbons (low boiling).
Cracking
involves breaking of C-C and C-H bonds.
cracking process
It produces low boiling alkanes and alkenes.
cracking
cracking produces
low boiling alkanes and alkenes
A small amount of__________ are also produced.
carbon and hydrogen
Carried out at high temperature and pressure in the absence of catalyst
Thermal Cracking
carried out in the presence of a catalyst at a much lower temperature and pressure
Catalytic Cracking
The_______of gasoline produced is high.
Octane number
external fuel is not required. The necessary heat is obtained by burning off the coke deposited on the catalyst itself, during the regeneration process.
Catalytic cracking
Indicates the % by volume of iso-octane in a mixture of iso-octane and heptane which exhibit the same characteristics of the fuel in a standard engine under a set of operating conditions
Octane Number
Common octane numbers for gasoline fuels used in ______ range from 87 to 95, with higher values for special high performance and racing cars.
automobile
Common octane numbers for gasoline fuels used in automobile range from _________, with higher values for special high performance and racing cars.
87 to 95
is a grey, hard, and porous fuel with a high carbon content and few impurities, made by heating coal or oil in the absence of air—a destructive distillation process.
coke
It is an important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves and forges when air pollution is a concern.
coke
is a shiny, black fossil fuel that contains impurities, emits smoke when burned, and produces less heat than coke
coal
is a dull, black by product of coal that burns hotter and cleaner.
coke
are responsible for the formation of an insoluble solid, commonly called deposits or gums, which sticks to the metal surfaces along the vehicle-fuel system, from the tank to the combustion chamber.
formed oxidation products
The formed oxidation products are responsible for the formation of an insoluble solid, commonly called
deposits or gums
Catalysts are selective in their action, and therefore, they permit cracking of only
high boiling hydrocarbons
are selective in their action, and therefore, they permit cracking of only high boiling hydrocarbons.
catalysts
a cracking chamber
reactor
Near the top of the reactor, there is a centrifugal separator
Cyclone
After cracking, the products are fractionated into
gases, gasoline, gas oils, an residual oils
, the spent catalyst is stripped of the adsorbed oil by passing steam and then decarbonized by a hot air blast, under controlled conditions.
regenerator
The finely divided catalyst bed (Al2O3 + SiO2) is fluidized by the upward passage of feed stock vapors (Heavy oil, gas oil, etc.) in a cracking chamber (called Reactor) maintained at 5500 C
Fluidized (moving) bed catalytic cracking
The catalyst (Al2O3 + SiO2) in the form of powder or pellets is placed on the grid in the catalytic chamber
Fixed-bed catalytic cracking
After some time, the catalyst gets deactivated due to the deposition of carbon and oil on its surface. Steam is passed through the riser column. The deactivated catalyst is led into a regenerator through which air is passed. Air oxidizes C to CO2 and steam removes the oil.
regeneration of catalyst
It is the process of upgrading gasoline (increasing its octane number) in presence of a catalyst
Catalytic Reforming
The feed stock (straight run gasoline) is preheated to remove S and N content to acceptable limits to avoid platinum catalyst being poisoned.
reforming process
process carried out to improve the octane number of petrol by bringing about changes in the structure of hydrocarbons.The changes in structure could be isomerization, cyclization or aromatization.
reforming
straight chain hydrocarbons are converted to branched hydrocarbons
Isomerization
straight chain hydrocarbons are converted to cyclic compounds
Cyclization
cyclic compounds are dehydrogenated.
Aromatization
is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit.
Internal Combustion Engine (ICE)