free 10 marks Flashcards
Why do ionic bonds have a high melting MP/BP
and why are they hard to break
High MP - strong electrostatic forces of attraction between oppositely charged ions, require a lot of energy to break
Why do small molecule (covalent) bonds have a low MP/BP and why are they hard to break
Low MP/BP, strong covalent bonds but weak IMF between molecules, which do not require a lot of energy to overcome
Why do Giant Covalent have such high BP/MP (e.g.: diamond, graphite)
High MP - strong covalent bonds which require a lot of energy to break
Metals BP/MP
High MP - strong electrostatic forces of attraction between positive metal ions and delocalised electrons, requires a lot of energy to break
Conducts electricity ionic
Solid does not conduct - ions are not free to move and carry a charge. Molten/dissolved does conduct as ions are free to move and carry a charge.
Conducts electricity small molecule
Does not conduct electricity as the substance does not contain any charged particles
Conducts electricity Metals
Positive ions and “sea” of delocalised electrons, which are free to carry a charge.
Conducts electricity giant covalent (Diamond)
Each C atom is bonded to 4 other C atoms and so does not conduct as there are no free electrons to carry a charge.
Conducts electricity giant covalent (Graphite)
Each C atom is bonded to 3 other C atoms and so there is 1 delocalised electron per C atom to carry a charge
Hardness Ionic
Lattice structure, strong electrostatic forces between oppositely charged ions in all directions.
Hardness giant covalent (diamond)
Giant lattice structure, strong covalent bonds in all directions
Hardness giant covalent (Graphite)
Soft - Hexagonal sheets of carbon atoms of strong covalent bonds, but weak IMF between layers, which do not require a lot of energy to overcome
Hardness metals (Pure metal)
Malleable - ordered layers of metal atoms which can easily slide past each other
Hardness metals (Alloy)
Hard - metal atoms of different sizes can distorted/disrupted layers, which cannot slide past each other