formulae, equations and amount of substance Flashcards
avagadros number
6.02 x 10^23
equation for number of particles
number of particles = number of moles x Avogadros constant
equation for the number of moles (including g and mr)
number of moles= mass / molar mass or atomic mass
equation for the number of moles (including concentration and volume)
number of moles= concentration x volume
cm3 to dm3 conversion
divide by 1000
equation for concentration (including mass and volume)
concentration= mass of substance / volume
what’s empirical formula?
the simplest whole number ratio of elements in a compound
steps to calculate empirical formula
- Determine mass or percentage of elements
- Divide the given masses or percentages by mass by their respective ar
- Divide the results by the smallest value
- Convert into the simplest whole number ratio
spectator ions are
ions that do not participate in a reaction
how to work out theoretical masses…
(e.g: how much CaO can be made when 34g of Ca is burnt completely in oxygen)
Steps:
1- write out a balanced equation.
2Ca+ 02 → 2 caO
2- workout the Mr /Ar of species involved
2 Ca = 40x2=80g 2 CaO = 56x2 = 112g
3. Divide Ca side by 80 to find 1g then multiply by 34 to get 34g and do the same for the CaO side.
80g / 80= 1g
1g x 34= 34g
112g / 80 = 1.4g
1.4g x 34= 47.6g
ANSWER = 47.6g
equation for the number of moles (including volume and molar gas volume)
number of moles= volume / molar gas volume (24)
ideal gas equation
pV = nRT
conversions
m - dm - cm
m2 - dm2 - cm2
m3 - dm3 - cm3
x10
x100
x1000
if converting the other way, decide by the same number
steps to working out the volume of a gas from an equation
(e.g- what volume of H2 is produced when 12g of K reacts with H2O at 100kPa of pressure and 289K, gas constant is 8.31 J K -1 mol -1)
I. write out balanced equation. 2K+2H20 → 2KOH+ H2
2. work out moles of K n= 12g/39 n= 0.31 mol of K
3. use equation tofind molar ratio of K: H2
2 moles of K react to produce 1 mole of H2
moles of H2 is 0.31/2 = 0.155 molesof H2
A use ideal gas equation to work out the volume
V= 0. 155x8.31 × 298/100000
v = 3.84 x 10-3
titration calculation steps (e.g: 18.3 cm3 of 0.25 mol dm-3 HCl was required to neutralise 25 cm3 оf КОН. calculate the concentration of KOH)
Steps: 1- write out a balanced equation HCl + KOH → KCl + H20
2-calculate number of moles in HCl
mol = 0.25x18.3x10-3 = 4. 58 x 10-3mol
3- use equation to find out molar ratio to work out moles of KOH
1:1 ratio between HCl and KOH.
so molar of KOH = mol HCl. so mol KOH = 4.58 x 10-3
4. now calculate the concentation using conc= mol / vol
4.58x10-3 / 25x10-3 = 0.18 mol dm-3