formulae, equations and amount of substance Flashcards

1
Q

avagadros number

A

6.02 x 10^23

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2
Q

equation for number of particles

A

number of particles = number of moles x Avogadros constant

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3
Q

equation for the number of moles (including g and mr)

A

number of moles= mass / molar mass or atomic mass

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4
Q

equation for the number of moles (including concentration and volume)

A

number of moles= concentration x volume

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5
Q

cm3 to dm3 conversion

A

divide by 1000

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6
Q

equation for concentration (including mass and volume)

A

concentration= mass of substance / volume

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7
Q

what’s empirical formula?

A

the simplest whole number ratio of elements in a compound

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8
Q

steps to calculate empirical formula

A
  1. Determine mass or percentage of elements
  2. Divide the given masses or percentages by mass by their respective ar
  3. Divide the results by the smallest value
  4. Convert into the simplest whole number ratio
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9
Q

spectator ions are

A

ions that do not participate in a reaction

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10
Q

how to work out theoretical masses…
(e.g: how much CaO can be made when 34g of Ca is burnt completely in oxygen)

A

Steps:
1- write out a balanced equation.
2Ca+ 02 → 2 caO
2- workout the Mr /Ar of species involved
2 Ca = 40x2=80g 2 CaO = 56x2 = 112g
3. Divide Ca side by 80 to find 1g then multiply by 34 to get 34g and do the same for the CaO side.
80g / 80= 1g
1g x 34= 34g

112g / 80 = 1.4g
1.4g x 34= 47.6g
ANSWER = 47.6g

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11
Q

equation for the number of moles (including volume and molar gas volume)

A

number of moles= volume / molar gas volume (24)

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12
Q

ideal gas equation

A

pV = nRT

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13
Q

conversions
m - dm - cm
m2 - dm2 - cm2
m3 - dm3 - cm3

A

x10
x100
x1000
if converting the other way, decide by the same number

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14
Q

steps to working out the volume of a gas from an equation
(e.g- what volume of H2 is produced when 12g of K reacts with H2O at 100kPa of pressure and 289K, gas constant is 8.31 J K -1 mol -1)

A

I. write out balanced equation. 2K+2H20 → 2KOH+ H2
2. work out moles of K n= 12g/39 n= 0.31 mol of K
3. use equation tofind molar ratio of K: H2
2 moles of K react to produce 1 mole of H2
moles of H2 is 0.31/2 = 0.155 molesof H2
A use ideal gas equation to work out the volume
V= 0. 155x8.31 × 298/100000
v = 3.84 x 10-3

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15
Q

titration calculation steps (e.g: 18.3 cm3 of 0.25 mol dm-3 HCl was required to neutralise 25 cm3 оf КОН. calculate the concentration of KOH)

A

Steps: 1- write out a balanced equation HCl + KOH → KCl + H20
2-calculate number of moles in HCl
mol = 0.25x18.3x10-3 = 4. 58 x 10-3mol
3- use equation to find out molar ratio to work out moles of KOH
1:1 ratio between HCl and KOH.
so molar of KOH = mol HCl. so mol KOH = 4.58 x 10-3
4. now calculate the concentation using conc= mol / vol
4.58x10-3 / 25x10-3 = 0.18 mol dm-3

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16
Q

standard solution calculations
(e.g- what mass of solid NaOH is required to make 250cm3 of 0.75mol dm-3 NaOH solution?)

A
  1. work out the number of moles of the solution you wanna
    make.
    moles= conc xvol
    mol = 0. 75x250x10-3 = 0.1875
  2. use number of moles from previous step to calculate the mass.
    formula mass of NaOH =40
    0.1875 x40 = 7.5g
17
Q

what’s meant by the molar volume of a gas?

A

volume /space occupied by one mole of a gas at a specified temperature and pressure/ standard conditions

18
Q

importance of atom economy…

A
  • High AE produce less wase & benefits the enviornment
  • High AE means that raw materials are used more efficiently - more sustainable
  • Higher AE = less by - products so less time + money spent separating these from the desirable product
19
Q

% atom economy equation

A

(Mass of desired product/total mass of reactants) x 100

20
Q

atom economy is…

A

how efficient a reaction is

21
Q

% yield equation

A

(actual yield/theoretical yield) x100

22
Q

% error equation

A

(uncertainty/ reading) x100

23
Q

uncertainty is…

A

half of the smallest increment of the equipment.
can measure in either direction

24
Q

reading a meniscus…

A

read at eye level and read at the bottom of the meniscus