Föreläsning 2 Flashcards
What are drivers to introduce Green “sustainable” Chemistry?
Reduce CO2 emissions, reduce waste
Reduce costs (e.g. avoid wasted rawmaterial)
Sustainable processing
What is the three steps for calculating atom economy?
What is the atom economy for making hydrogen
(H2) by reacting coal (C) with steam (H2O)?
1. Which are the reactants and products?
2. Do you have any by-products? (by products are
not included in the calculation!)
3. Balance the equation.
3. Add the molecular weight of reactants and
product.
AE = [mw of product] / [sum of mw of reactants] ×
100
How do you calculate Atom economy for this reaction?
A + B –> C
Atom economy (%) = ([mw of product C] / [mw of A + mw of B])*100
Formula internet: (MW desired product)/(Sum of MW of all reactants) * 100
How do you calculate the Atom economy for this reaction?
A+B –> C
C+D –> E
E+F –> G
AE (%) = ([MW of G]/[MW A+MW B+ MWD + MW F])×100
So skip middle products in the denominator
Example 1:
What is the atom economy for making hydrogen
(H2) by reacting coal (C) with steam (H2O)?
C + H2O ≠ H2 + CO2
Balansera C + 2H2O –> 2H2 + CO2
AE = (MW summan produkter)/(MW produkter) (ej biprodukter) )
AE = 4/(12+4+32) <-> AE = 0.083 Svar 8.3 %
What types of yields are there?
*Theoretical yield: is what you calculate
the yield will be using the balanced
chemical reaction. (g)
* Actual yield is what you actually get in a
chemical reaction. (g)
* Percent yield: (actual
yield/theoretical)x100%