Forces within Molecules Flashcards
Temporary dipole-dipole forces
Very weak and occur in all molecular substances
Attraction between nuclei in one molecule and valence electrons in another molecule.
Only intermolecular force acting in non-polar substances.
Permanent dipole-dipole forces
electronegative atoms draw more electron density towards them creating a permanent dipole within the molecule. Electrostatically attracted to the opposite dipole on neighbouring molecules.
Hydrogen bonding
Strongest intermolecular attraction
Occurs between molecules where H is connected to N, O or F.
Intermolecular bonding
Bonding between molecules
Intramolecular bonding
Bonding within a molecule
Intramolecular covalent forces
Holds atoms together as molecules so they are very strong
Intermolecular attractions
Hold molecules together as a solid so they are comparatively weaker
Non polar substance melting and boiling points
Low because TDF are weak
Polar substance melting and boiling points
Higher than non-polar but lower than ionic compounds