Forces between molecules- van der Waals' Flashcards
how does the strength of intermolecular forces compare to ionic or covalent bonds?
weaker
what are the three type of intermolecular force?
- van der Waals’
- permanent dipole-dipole
- hydrogen bonds
in what type of particles are van der Waals’ forces the predominant force?
non-polar particles- those that do not have a permanent dipole moment
what are some species that have an even electron distribution (van der Waals’ forces are predominant)?
- single atoms
- molecules of the same element
- hydrocarbons
- symmetrical molecules
what are van der Waals’ forces caused by?
the attraction between temporary dipoles
when is a temporary dipole formed?
when there is a momentary shift in electron density within the molecule’s electron cloud
how do temporary dipoles affect neighbouring molecules?
cause a distortion in the charge cloud of neighbouring molecules- an induced temporary dipole
how does the size of an atom or molecule affect induced dipole forces? why?
induced dipole forces (van der Waals’ forces) become stronger the larger the atom or molecule- because larger electron clouds are easier to deform
boiling point in compounds held together by van der Waals’ forces? why?
low boiling point- forces are very weak and require little energy to break